Boron(III) Complexes with N,N `- and N,O-Heterocyclic Ligands: Synthesis and Spectroscopic Properties / Lipunova Galina N.,Nosova Emiliya V.,Charushin Valery N.,Chupakhin Oleg N. // COMMENTS ON INORGANIC CHEMISTRY. - 2016. - V. 36, l. 5. - P. 245-303.

ISSN/EISSN:

0260-3594 / 1548-9574

Type:

Review

Abstract:

This review is focused on consideration of effects of the nature of N,N'-and N,O-bidentate ligands on the structure and optical properties of their B(III) complexes. It has been established that B(III) complexes with asymmetric N,N'-and N,O-bidentate ligands, such as ortho-hydroxyphenyl substituted azaheterocycles and heteryl-beta-ketoimines, exhibit large Stokes shifts, enhanced intensity, and extended range for luminescence in solutions as well as in solid state, comparable with characteristics of the family of BODIPYs derivatives. Complexes of some bidentate ligands can be considered as promising fluorophores for applications in biomedical imaging, electroluminescent, solar cell devices, and other fields.

Author keywords:

B(III) complexes; BODIPY; asymmetric NN `-ligands; (o-hydroxyphenyl) substituted azaheterocycles; heteryl-beta-ketoimines; structure; optical properties; photoluminescence C-H ARYLATION; SOLID-STATE FLUORESCENCE; BODIPY DYES; PHOTOPHYSICAL PROPERTIES; SOLAR-CELLS; OPTICAL-PROPERTIES; BORATE COMPLEXES; DIPYRROMETHENES BODIPYS; DIFLUORIDE COMPLEXES; CRYSTAL-STRUCTURE

DOI:

10.1080/02603594.2016.1153470

Web of Science ID:

ISI:000382258900001

Соавторы в МНС:

Другие поля

Поле	Значение
Publisher	TAYLOR \& FRANCIS LTD
Address	2-4 PARK SQUARE, MILTON PARK, ABINGDON OR14 4RN, OXON, ENGLAND
Language	English
EISSN	1548-9574
Keywords-Plus	C-H ARYLATION; SOLID-STATE FLUORESCENCE; BODIPY DYES; PHOTOPHYSICAL PROPERTIES; SOLAR-CELLS; OPTICAL-PROPERTIES; BORATE COMPLEXES; DIPYRROMETHENES BODIPYS; DIFLUORIDE COMPLEXES; CRYSTAL-STRUCTURE
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
Author-Email	emily74@rambler.ru
Funding-Acknowledgement	Russian Foundation for Basic Research {[}14-03-00340]; Ural Division of Russian Academy of Sciences {[}15-21-3-7]
Funding-Text	This work was supported by the Russian Foundation for Basic Research (grant 14-03-00340) and Ural Division of Russian Academy of Sciences (project 15-21-3-7).
Number-of-Cited-References	85
Usage-Count-Last-180-days	10
Usage-Count-Since-2013	22
Journal-ISO	Comments Inorganic Chem.
Doc-Delivery-Number	DU5NQ