Simultaneous determination of aliphatic acids and aldehydes in aqueous media by reaction gas chromatography / Pervova M. G.,Chizhov D. L.,Saloutin V. I. // JOURNAL OF ANALYTICAL CHEMISTRY. - 2016. - V. 71, l. 10. - P. 1041-1045.

ISSN/EISSN:

1061-9348 / 1608-3199

Type:

Article

Abstract:

A procedure is developed for the gas chromatographic determination of lower aldehydes as dibutoxyalkanes and carboxylic acids as butyl esters by the reaction with tributyl borate in an aqueous medium. Derivatization conditions were optimized. The procedure was used to determine side products in glyoxal synthesized by the catalytic oxidation of ethylene glycol.

Author keywords:

gas chromatography; aldehydes; carboxylic acids; tributyl borate; derivatization CARBOXYLIC-ACIDS; CARBONYL-COMPOUNDS; LIQUID-CHROMATOGRAPHY; KETOCARBOXYLIC ACIDS; DICARBOXYLIC-ACIDS; MASS-SPECTROMETRY; AEROSOL SAMPLES; DERIVATIZATION; DICARBONYLS; DERIVATIVES

DOI:

10.1134/S1061934816100099

Web of Science ID:

ISI:000385253700007

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	OCT
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3199
Keywords-Plus	CARBOXYLIC-ACIDS; CARBONYL-COMPOUNDS; LIQUID-CHROMATOGRAPHY; KETOCARBOXYLIC ACIDS; DICARBOXYLIC-ACIDS; MASS-SPECTROMETRY; AEROSOL SAMPLES; DERIVATIZATION; DICARBONYLS; DERIVATIVES
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Analytical
Author-Email	pervova@ios.uran.ru
Number-of-Cited-References	28
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	9
Journal-ISO	J. Anal. Chem.
Doc-Delivery-Number	DY6QT