Study of Polyfunctional Diazo Compounds Reactivity in Heterocyclization by the Method of Intramolecular Competitive Reactions / Bakulev V.A., Morzherin Y.Yu., Dankova E.F., Kolobov M.Yu., Shafran Y.M., Lebedev A.T. // Bulletin des Sociétés Chimiques Belges. - 1993. - V. 102, l. 7. - P. 493-502.

ISSN:
00379646
Type:
Article
Abstract:
New method for the study of reactivity of highly reactive compounds was proposed and applied to determine the effect of substituents in α‐diazoacetamidines, and ‐imidates. The introduction of electron‐releasing groups to the nitrogen atom of the amidine, and imidate functions was shown to increase the reactivity of the substances studied. The results obtained are in good agreement with the heteroelectrocyclic mechanism suggested for the cyclization of these compounds. Copyright © 1993 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
Author keywords:
Index keywords:
нет данных
DOI:
10.1002/bscb.19931020708
Смотреть в Scopus:
https://www.scopus.com/inward/record.uri?eid=2-s2.0-0000555878&doi=10.1002%2fbscb.19931020708&partnerID=40&md5=baff17dc456fcc8c84ca9736f464ebcf
Соавторы в МНС:
Другие поля
Поле Значение
Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-0000555878&doi=10.1002%2fbscb.19931020708&partnerID=40&md5=baff17dc456fcc8c84ca9736f464ebcf
Affiliations Department of Chemical Technology, Ural State Technical University - UPI, Ekaterinburg, 620002, Russian Federation; Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, 119899, Russian Federation
References Regitz, M., Arnold, B., Danion, D., Schubert, H., Fusser, G., (1981) Bull. Soc. Chim. Belg., 90, p. 615; Bakulev, V.A., Mokrushin, V.S., (1986), p. 811. , Khim. Geterotsikl. Soed. (Eng. Ed.); Keimatsu, S., Satoda, Y., (1935) Yakugaku Zasshi., 55, p. 233; L'abbe, G., (1990) Bull. Soc. Chim. Belg., 99, p. 281; Pannel, K., Mayr, A., van Der Veer, D., Transition metal heterocyclic chemistry. 7. Stabilization of an .alpha.-diazo thioketone (a new class of compound) by a unique linear triiron cluster (1983) Journal of the American Chemical Society, 105, p. 6186; Bakulev, V.A., Gloriozov, I.P., (1989), p. 504. , Khim. Geterotsikl. Soed., (4); Kulobov, M.Yu., Morzhorin, Bakulev, V.A., Mokrushin, V.S., (1991), p. 1521. , Khim. Geterotsikl. Soed., (11); Dankova, E.F., Bakulev, V.A., Krut'ko, D.P., (1991), p. 775. , Khim. Geterotsikl. Soed., (6); Dankova, E.F., Bakulev, V.A., Morzherin, (1992), pp. 1106-1112. , Khim. Geterotsikl. Soed., (3); Dankova, E.F., Kolobov, M.Yu., Mokrushin, V.S., ‘Now Approach to the Study of the 2‐Diazoimines and 2‐Diazothione Reactivity’ (1989) ‘Sixth European Symposium on Organic Chemistry’, p. 309. , Beograde, Yugoslavia; Ingold, C.K., (1969) ‘Structure and Mechanism in Organic Chemistry’, , 2 Ed., Cornell Univ. Press; Cullen, K.E., Sharp, J.T., (1991), p. 658. , J. Chem. Soc., Chem. Commun; Shafran, Yu.M., Bakulev, V.A., Mokrushin, V.S., Alekseev, S.G., (1984), p. 1266. , Khim. Geterotsikl. Soed., (9); (1970) ‘The Chemistry of Amides’., , Zabicky, J., Intersc., London; Woodward, R.B., Hoffmann, R., Stereochemistry of Electrocyclic Reactions (1965) Journal of the American Chemical Society, 87, p. 395; Brewbaker, J.L., Hart, H., (1969) J. Am. Chem. Soc., 91, p. 711; Bakulev, V.A., Kartsev, V.G., Mokrushin, V.S., (1989), p. 1443. , Khim. Geterotsikl. Soed. (Eng. Ed.).,. (11); Burke, Elguero, J., Leroy, G., Sana, M., (1976) J. Am. Chem. Soc., 98, p. 1685; Nguen, M.T., Ha, T.‐K., O'Ferrall, R.A.M., (1990) J. Org. Chem., 55, p. 3251
Correspondence Address Bakulev, V.A.; Department of Chemical Technology, Ural State Technical University - UPI, Ekaterinburg, 620002, Russian Federation
Language of Original Document English
Abbreviated Source Title Bull. Soc. Chim. Belg.
Source Scopus