Electrode potentials of tungsten in fused alkali chlorides / Ivanov A.B., Volkovich V.A., Poskryakov D.A., Vasin B.D., Griffiths T.R. // AIP Conference Proceedings. - 2016. - V. 1767, l. .

ISSN:
0094243X
Type:
Conference Paper
Abstract:
Anodic dissolution of tungsten was studied at 823-1173 K in the melts based on NaCl-CsCl, NaCl-KCl-CsCl and LiCl-KCl-CsCl eutectic mixtures. The process results in the formation of W(IV) ions. Prolonged contact with silica results in oxidation W(IV) ions and decreasing tungsten concentration in the electrolyte due to formation of volatile higher oxidation state chloro- and oxychloro-species. Tungsten electrode potentials were measured in NaCl-CsCl and NaCl-KCl-CsCl based melts using potentiometry. © 2016 Author(s).
Author keywords:
Index keywords:
нет данных
DOI:
10.1063/1.4962594
Смотреть в Scopus:
https://www.scopus.com/inward/record.uri?eid=2-s2.0-84991693733&doi=10.1063%2f1.4962594&partnerID=40&md5=7cdaf1e2169085974bc37fb88a08ac6a
Соавторы в МНС:
Другие поля
Поле Значение
Art. No. 020010
Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-84991693733&doi=10.1063%2f1.4962594&partnerID=40&md5=7cdaf1e2169085974bc37fb88a08ac6a
Affiliations Department of Rare Metals and Nanomaterials, Institute of Physics and Technology, Ural Federal University, Ekaterinburg, Russian Federation; Energy Process Developments Ltd., London, United Kingdom
References Shkol'Nikov, S.N., Manenkov, M.I., Yarmolovich, A.K., (1973) Zh. Prikl. Khim., 46, pp. 1918-1921; Manenkov, M.I., Shkol'Nikov, S.N., (1974) Izv. Vuzov. Tsvet. Metallurgiya, (1), pp. 65-68; Smirnov, M.V., (1973) Electrode Potentials in Fused Chlorides, pp. 169-170. , (Nauka, Moscow), (in Russian)
Correspondence Address Ivanov, A.B.; Department of Rare Metals and Nanomaterials, Institute of Physics and Technology, Ural Federal UniversityRussian Federation; email: chuvasch@yandex.ru
Editors Rempel A.A.Volkovich V.A.
Publisher American Institute of Physics Inc.
Conference name 3rd International Young Researchers' Conference: Physics, Technologies and Innovation, PTI 2016
Conference date 16 May 2016 through 20 May 2016
Conference code 123961
ISBN 9780735414259
Language of Original Document English
Abbreviated Source Title AIP Conf. Proc.
Source Scopus