High-temperature corrosion of metals in the salt and metallic melts containing rare earths / Karpov V.V., Abramov A.V., Zhilyakov A.Yu., Belikov S.V., Volkovich V.A., Polovov I.B., Rebrin O.I. // AIP Conference Proceedings. - 2016. - V. 1767, l. .

ISSN:
0094243X
Type:
Conference Paper
Abstract:
A complex of independent methods was employed to study the corrosion resistance of molybdenum, zirconium, tantalum and tungsten in chloride, chloride-fluoride and fluoride-oxide melts based on LiCl, CaCl2, NaCl- KCl, LiF, and containing rare earths. Tests were conducted for 30 h at 750-1050 °C. The metals showed excellent corrosion resistance in fused chlorides (the corrosion rates were below 0.0005 g/(m2 h). Despite the presence of chemically active fluoride ions in the chloride-fluoride melts, the metals studied also showed very low corrosion rates, except molybdenum, for which the rate of corrosion was 0,8 g/(m2 h). The corrosion resistance of tantalum was considerably reduced in the fluoride-oxide melts; the corrosion rate was over 1 g/(m2 h) corresponding to the 8-th grade of stability and placing tantalum to the group of "low stability" materials. © 2016 Author(s).
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DOI:
10.1063/1.4962595
Смотреть в Scopus:
https://www.scopus.com/inward/record.uri?eid=2-s2.0-84991629021&doi=10.1063%2f1.4962595&partnerID=40&md5=13ba6e5af86aa7e501f68da3cb00975e
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Art. No. 020011
Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-84991629021&doi=10.1063%2f1.4962595&partnerID=40&md5=13ba6e5af86aa7e501f68da3cb00975e
Affiliations Department of Physical and Chemical Methods of Analysis, Ural Federal University, Ekaterinburg, Russian Federation; Department of Heat Treatment and Physics of Metals, Ural Federal University, Ekaterinburg, Russian Federation; Department of Rare Metals and Nanomaterials, Ural Federal University, Ekaterinburg, Russian Federation
Funding Details 14.581.21.0002, Ministry of Education and Science of the Russian Federation
Funding Text The study was financially supported by the Ministry of Education and Science of the Russian Federation within the framework of subsidizing agreement of September 29, 2014 (No. 14.581.21.0002, unique agreement identifier RFMEFI58114X0002) of the Federal Target Program Research and Development in Priority Directions of theProgress of the Scientific and Technological Complex of Russia for the Years 20142020.
References Ozeryanaya, I.N., (1985) Metal Science and Heat Treatment, 27, pp. 184-187; Hu, X.-W., Wang, Z.-W., Gao, B.-L., Shi, Z.-N., (2008) Journal of Northeastern University, 29, pp. 1294-1297; Chen, D., Yan, S., Li, Z., Wang, Z., Pang, S., Wang, X., Xu, L., (2009) Journal of the Chinese Rare Earth Society, 27, pp. 302-305; Pang, S., Yan, S., Li, Z., Chen, D., Xu, L., Zhao, B., (2011) Chinese Journal of Rare Metals, 35, pp. 440-450; Chen, D., Yan, S., Li, Z., Pang, S., Xu, L., Guo, X., (2011) Journal of the Chinese Rare Earth Society, 29, pp. 769-772; Zhang, X.L., Liu, H.X., Zheng, X., Zhe, W.H., Jin, L., Jue, Z., (2013) Advanced Materials Research, 800, pp. 496-500; Lyakishev, N.P., (1996) Phase Diagrams of Binary Metallic Systems, 1, pp. 928-973. , (Mashinostroenie, Moskow), (in Russian)
Correspondence Address Karpov, V.V.; Department of Physical and Chemical Methods of Analysis, Ural Federal UniversityRussian Federation; email: karpov610@yandex.ru
Editors Rempel A.A.Volkovich V.A.
Publisher American Institute of Physics Inc.
Conference name 3rd International Young Researchers' Conference: Physics, Technologies and Innovation, PTI 2016
Conference date 16 May 2016 through 20 May 2016
Conference code 123961
ISBN 9780735414259
Language of Original Document English
Abbreviated Source Title AIP Conf. Proc.
Source Scopus