Magnetic Properties of Ti3O5 with Chromium Additions / Shveikin G.P., Kellerman D.G., Gorshkov V.S., Perelyaev V.A. // ZAAC ‐ Journal of Inorganic and General Chemistry. - 1987. - V. 544, l. 1. - P. 21-27.

ISSN:

00442313

Type:

Article

Abstract:

Magnetic susceptibility measurements were used to study solid solutions Ti3−xCrxO5 (0 ⩽ × ⩽ 0.17). Contributions to magnetic susceptibility for the α‐phase were defined by the statistical analysis of the experimental data. A conclusion was made on the varing character of exchange interactions in α‐Ti3−xCrxO5 with increasing Cr content. In the present work, the information given indicates that Cr stabilizes the high‐temperature α‐Ti3O5 and decreases the temperature of semiconductor‐metal phase transition. Magnetic properties of low‐temperature α‐Ti3O5 phase with chromium addition are shown to be explained by the existence of exchange‐coupled pairs Ti3+Cr3+. Copyright © 1987 Verlag GmbH & Co. KGaA, Weinheim

Author keywords:

Index keywords:

нет данных

DOI:

10.1002/zaac.19875440103

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https://www.scopus.com/inward/record.uri?eid=2-s2.0-84944148176&doi=10.1002%2fzaac.19875440103&partnerID=40&md5=bce268c203eec64553f06bb8fe8d79e2

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Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84944148176&doi=10.1002%2fzaac.19875440103&partnerID=40&md5=bce268c203eec64553f06bb8fe8d79e2
Affiliations	Inst. f. Chemie (U.N.Z) d. AdW d. UdSSR, Pervomai-Str. 91, Swerdlowsk, 620145
References	Mulay, L.N., Danley, W.I., (1970) J. Appl. Phys., 41, p. 877; Asbrink, S., Magneli, A., Crystal structure studies on trititanium pentoxide, Ti3O5 (1959) Acta Crystallographica, 12, p. 575; Kellerman, D.G., Perelyaev, V.A., Palkin, A.P., Shveikin, G.P., (1983) Zh. Neorg. Khim., 28, p. 1645; Kellerman, D.G., Perelyaev, V.A., Shveikin, G.P., (1985) Fasovoe prevrazshenie v Ti3O5, p. 50. , pre‐print, UNC AN SSSR, Sverdlovsk; Keys, L.K., (1967) J. Phys. Soc. Jap., 23, p. 478; Vonsovskii, S.V., (1971) Magnetism, p. 1032. , Moskva, Nauka; Mott, N.F., (1979) Perekhodi metall‐isolyator, p. 121. , Moskva, Mir; Dumas, J., Schlenker, C., Natoli, P.C., (1975) Solid State Commun., 16, p. 493
Correspondence Address	Shveikin, G.P.; Inst. f. Chemie (U.N.Z) d. AdW d. UdSSR, Pervomai-Str. 91, Swerdlowsk, 620145
Language of Original Document	English
Abbreviated Source Title	Z. Anorg. Allg. Chem.
Source	Scopus