Direct C[sbnd]C coupling of phthalazine-N-oxide with the carboranyl anion – An original approach to C-modification of carboranes / Varaksin M.V., Galliamova L.A., Stepanova O.A., Eltsov O.S., Chupakhin O.N., Charushin V.N. // Journal of Organometallic Chemistry. - 2017. - V. 830, l. . - P. 93-99.

ISSN:
0022328X
Type:
Article
Abstract:
An original transition metal-free approach based on the direct C[sbnd]C coupling of phtalazine-N-oxide with the carboranyl anion has been developed. A series of the novel C-modified closo-carboranes such as 1-(2-oxido-3-acyl-3,4-dihydrophtalazinyl-4-yl)-1,2-dicarba-closo-dodecaboranes and 1-(2-formylbenzyl)-1,2-dicarba-closo-dodecaborane have been obtained. The synthesized boron clusters could be of interest as promising building blocks in design of BNCT delivery agents. © 2016
Author keywords:
Carboranes; C[sbnd]C coupling; Phthalazine-N-oxide
Index keywords:
нет данных
DOI:
10.1016/j.jorganchem.2016.11.0
Смотреть в Scopus:
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85006789489&doi=10.1016%2fj.jorganchem.2016.11.032&partnerID=40&md5=b40792b32f0b8bd08cd03b45806f459f
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Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-85006789489&doi=10.1016%2fj.jorganchem.2016.11.032&partnerID=40&md5=b40792b32f0b8bd08cd03b45806f459f
Affiliations Ural Federal University, 19 Mira Str., Ekaterinburg, Russian Federation; Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 S. Kovalevskaya Str., Ekaterinburg, Russian Federation
Author Keywords Carboranes; C[sbnd]C coupling; Phthalazine-N-oxide
Funding Details 16-03-00958, RFBR, Russian Foundation for Basic Research; 4.6351.2017/BCh, Minobrnauka, Ministry of Education and Science of the Russian Federation
Funding Text The research was supported by the Ministry of Education and Science of the Russian Federation (Project № 4.6351.2017/BCh, synthesis of carboranes 4a–f) and the Russian Foundation for Basic Research (Project № 16-03-00958, synthesis of carborane 5).
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Correspondence Address Chupakhin, O.N.; Ural Federal University, 19 Mira Str., Russian Federation; email: chupakhin@ios.uran.ru
Publisher Elsevier B.V.
CODEN JORCA
Language of Original Document English
Abbreviated Source Title J. Organomet. Chem.
Source Scopus