Magnetic properties of iron oxide-based nanoparticles: Study using Mössbauer spectroscopy with a high velocity resolution and magnetization measurements / Ushakov M.V., Oshtrakh M.I., Felner I., Semenova A.S., Kellerman D.G., Šepelák V., Semionkin V.A., Morais P.C. // Journal of Magnetism and Magnetic Materials. - 2017. - V. 431, l. . - P. 46-48.

ISSN:
03048853
Type:
Article
Abstract:
We review the results of the study of magnetite, maghemite and nickel ferrite nanoparticles (NPs), applying for magnetic fluids, using Mössbauer spectroscopy with a high velocity resolution and magnetization measurements. The Mössbauer spectra of these NPs were fitted using a large number of magnetic sextets reflecting NPs complicity. The presence of polar molecules at the magnetite surface in magnetic fluid increases the NPs magnetic moment and the median hyperfine magnetic field. However, surface coating of maghemite NPs with dimeracptosuccinic acid decreases the median hyperfine magnetic field. An example of nickel ferrite NPs demonstrated a new physical model based on distribution of Ni2+ in the local microenvironment of Fe3+ which can explain a large number of magnetic sextets in the Mössbauer spectra measured with a high velocity resolution. © 2016 Elsevier B.V.
Author keywords:
Magnetic fluids; Magnetite, maghemite and nickel ferrite nanoparticles; Magnetization measurements; Mössbauer spectroscopy
Index keywords:
Ferrite; Magnetic fields; Magnetic fluids; Magnetic moments; Magnetism; Magnetite; Magnetite nanoparticles; Magnetization; Nanoparticles; Nickel; Hyperfine magnetic fields; Magnetic sextet; Magnetite
DOI:
10.1016/j.jmmm.2016.09.054
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-84994711545&doi=10.1016%2fj.jmmm.2016.09.054&partnerID=40&md5=6da18c62be393d307af5a31ed409ef14
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Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-84994711545&doi=10.1016%2fj.jmmm.2016.09.054&partnerID=40&md5=6da18c62be393d307af5a31ed409ef14
Affiliations Institute of Physics and Technology, Ural Federal University, Ekaterinburg, Russian Federation; Racah Institute of Physics, The Hebrew University, Jerusalem, Israel; Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Ekaterinburg, Russian Federation; Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen, Germany; School of Chemistry and Chemical Engineering, Anhui University, Hefei, China; Universidade de Brasília, Instituto de Física, DF, Brasília, Brazil
Author Keywords Magnetic fluids; Magnetite, maghemite and nickel ferrite nanoparticles; Magnetization measurements; Mössbauer spectroscopy
Funding Details Project No. 2085, Minobrnauka, Ministry of Education and Science of the Russian Federation
Funding Text We thank Dr. B. Senthilkumar and Dr. R. Kalai Selvan (Brahartiar University, Coimbatore, India) for preparation of nickel ferrite nanoparticles. This work was supported in part by the Ministry of Education and Science of the Russian Federation (Project No. 2085) and by Act 211 Government of the Russian Federation, contract № 02.A03.21.0006.
References Arruebo, M., Fernández-Pacheco, R., Ibarra, M.R., Santamaría, J., (2007) NanoToday, 2, pp. 22-32; Pankhurst, Q.A., Connoly, J., Jones, S.K., Dobson, J., (2003) J. Phys. D: Appl. Phys., 36, pp. R167-R181; Greneche, J.M., (2003) Hyperfine Interact., 148/149, pp. 79-89; Morais, P.C., (2008) Hyperfine Interact., 181, pp. 1-12; Papaefthymiou, G.C., Rabias, I., Fardis, M., Devlin, E., Boukos, N., Tsitrouli, D., Papavassiliou, G., (2009) Hyperfine Interact., 190, pp. 59-66; Oshtrakh, M.I., Šepelák, V., Rodriguez, A.F.R., Semionkin, V.A., Ushakov, M.V., Santos, J.G., Silveira, L.B., Morais, P.C., (2013) Spectrochim. Acta Part A: Mol. Biomol. Spectrosc., 100, pp. 94-100; Oshtrakh, M.I., Ushakov, M.V., Semenova, A.S., Kellerman, D.G., Šepelák, V., Rodriguez, A.F.R., Semionkin, V.A., Morais, P.C., (2013) Hyperfine Interact., 219, pp. 19-24; Oshtrakh, M.I., Ushakov, M.V., Semionkin, V.A., Lima, E.C.D., Morais, P.C., (2014) Hyperfine Interact., 226, pp. 123-130; Oshtrakh, M.I., Ushakov, M.V., Šepelák, V., Semionkin, V.A., Morais, P.C., (2016) Spectrochim. Acta Part A: Mol. Biomol. Spectrosc., 152, pp. 666-679; Oshtrakh, M.I., Ushakov, M.V., Senthilkumar, B., Kalai Selvan, R., Sanjeeviraja, C., Felner, I., Semionkin, V.A., (2013) Hyperfine Interact., 219, pp. 7-12; Oshtrakh, M.I., Semionkin, V.A., (2013) Spectrochim. Acta Part A: Mol. Biomol. Spectrosc., 100, pp. 78-87
Correspondence Address Oshtrakh, M.I.; Institute of Physics and Technology, Ural Federal UniversityRussian Federation; email: oshtrakh@gmail.com
Publisher Elsevier B.V.
CODEN JMMMD
Language of Original Document English
Abbreviated Source Title J Magn Magn Mater
Source Scopus