Synthesis of 1,3,4,6-tetraoxo compounds / Mukovoz P.P., Koz’minykh V.O., Gorbunova A.V., Slepukhin P.A., El’tsov O.S., Ganebnykh I.N., Kuzmin A.V. // Russian Journal of General Chemistry. - 2016. - V. 86, l. 11. - P. 2427-2436.

ISSN:

10703632

Type:

Article

Abstract:

The two-step method of synthesis of 1,3,4,6-tetraoxocompounds with different terminal substituents is developed. By condensation of alkyl methyl ketones with dimethyl oxalate new 1,6-dialkyl-substituted 1,3,4,6-tetraoxohexanes are obtained. The esters of 3,4,6-trioxoalkanoic acids are synthesized by the condensation reaction of alkyl acetates with dialkyl oxalates and alkyl methyl ketones. By the reaction of ethyl acetate with diethyl oxalate and methyl acetate the mixed diester of 3,4-dioxo-1,6-hexanedioic (ketipic) acid has been first prepared. Specific structural features of the synthesized compounds are discussed basing on the data of the IR, NMR, and XRD diffraction (XRD) analysis. © 2016, Pleiades Publishing, Ltd.

Author keywords:

1,6-dialkyl-1,3,4,6-tetraoxohexanes; esters of 3,4-dihydroxy-2,4-hexadiene-1,6-dioic and 3,4-dihydroxy-6-oxo-2,4-alkadienoic acids

Index keywords:

нет данных

DOI:

10.1134/S1070363216110050

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85006515966&doi=10.1134%2fS1070363216110050&partnerID=40&md5=f8f2976ffc5d11ae03e37d96bef47a9b

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Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-85006515966&doi=10.1134%2fS1070363216110050&partnerID=40&md5=f8f2976ffc5d11ae03e37d96bef47a9b
Affiliations	Orenburg Branch, Moscow Technological Institute, pr. Pobedy 75, Orenburg, Russian Federation; Perm State Humanitary Pedagogical University, Perm, Russian Federation; Orenburg State University, Orenburg, Russian Federation; I.Ya. Postovskii Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences, Yekaterinburg, Russian Federation; Ural Federal University named after the first President of Russia B.N. Yeltsin, Yekaterinburg, Russian Federation; Institute of Solid State Physics of Russian Academy of Sciences, Chernogolovka, Russian Federation
Author Keywords	1,6-dialkyl-1,3,4,6-tetraoxohexanes; esters of 3,4-dihydroxy-2,4-hexadiene-1,6-dioic and 3,4-dihydroxy-6-oxo-2,4-alkadienoic acids
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Correspondence Address	Mukovoz, P.P.; Orenburg Branch, Moscow Technological Institute, pr. Pobedy 75, Russian Federation; email: mpp27@mail.ru
Publisher	Maik Nauka Publishing / Springer SBM
CODEN	RJGCE
Language of Original Document	English
Abbreviated Source Title	Russ. J. Gen. Chem.
Source	Scopus