Nanostructured ZnS with random close-packed structure: Synthesis, formation rate, and crystal structure study / Vorokh A. S.,Kozhevnikova N. S.,Uritskaya A. A.,Bamburov V. G. // DOKLADY PHYSICAL CHEMISTRY. - 2016. - V. 470, l. 2. - P. 141-144.

ISSN/EISSN:

0012-5016 / 1608-3121

Type:

Article

Abstract:

The chemical precipitation of nanocrystalline ZnS from aqueous alkaline solutions containing zinc ethylenediamine complex salt Zn(En)(2+) and thiocarbonic acid diamide N2H4CS was studied in the course of time in terms of formal chemical kinetics. The ZnS formation rate was found to depend on the concentration of precipitation agent (N2H4CS) and to decrease with increasing the ligand (ethylenediamine) concentration, whereas the pH dependence is less pronounced. The size of resulting ZnS nanoparticles does not exceed 5 nm, and their crystal structure was identified as a random close packed structure.

Author keywords:

NANOCRYSTALS; NANOPARTICLES; TEMPERATURE; SHAPE

DOI:

10.1134/S0012501616100031

Web of Science ID:

ISI:000387478000001

Соавторы в МНС:

Другие поля

Поле	Значение
Month	OCT
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3121
Keywords-Plus	NANOCRYSTALS; NANOPARTICLES; TEMPERATURE; SHAPE
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Physical
Author-Email	vorokh@ihim.uran.ru kozhevnikova@ihim.uran.ru
ResearcherID-Numbers	Vorokh, Andrey/D-1118-2010 Bamburov, Vitaliy/J-3241-2017
ORCID-Numbers	Vorokh, Andrey/0000-0002-2384-5378
Funding-Acknowledgement	Russian Foundation for Basic Research {[}16-03-00566]
Funding-Text	This work was supported by the Russian Foundation for Basic Research (project no. 16-03-00566).
Number-of-Cited-References	14
Usage-Count-Since-2013	1
Journal-ISO	Dokl. Phys. Chem.
Doc-Delivery-Number	EB6FW