Magnetic and soft X-ray absorption spectroscopy characterization of Mn and Co doped lithium nickel phosphate LiNiPO4 / Galakhov V.R., Mesilov V.V., Shamin S.N., Urusova N.V., Barykina Y.A., Kellerman D.G. // Physica Status Solidi (B) Basic Research. - 2017. - V. 254, l. 4.

ISSN:
03701972
Type:
Article
Abstract:
Measurements of magnetic susceptibility as a function of temperature and soft metal L2,3 and oxygen K X-ray absorption spectra were applied for the characterization of Mn and Co doped LiNiPO4. It was established on the basis of measurements of magnetic susceptibility as a function of temperature that the replacement of 10% of Ni by Mn in LiNiPO4 increases the antiferromagnetic phase transition temperature from 21.3 to 22.8 K, while the same amount of cobalt decreases the Néel temperature to 21.0 K. The experimental Ni, Mn, and Co L2,3 X-ray absorption spectra compared with the results of crystal field atomic multiplet calculations showed that Ni, Mn, and Co ions are in the 2 + valence states. According to our O K X-ray absorption spectra, there are no doping states in the band gap of Mn and Co doped lithium nickel phosphate. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Author keywords:
crystal field multiplet calculations; LiNiPO4; Magnetic susceptibility; Mn and Co impurities; Néel temperature; X-ray absorption spectra
Index keywords:
нет данных
DOI:
10.1002/pssb.201600264
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-84994895716&doi=10.1002%2fpssb.201600264&partnerID=40&md5=38c1c55222906706a566c8792b59ba5f
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Art. No. 1600264
Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-84994895716&doi=10.1002%2fpssb.201600264&partnerID=40&md5=38c1c55222906706a566c8792b59ba5f
Affiliations M. N. Miheev Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences, Yekaterinburg, Russian Federation; Ural Federal University, Yekaterinburg, Russian Federation; Institute of Solid State Chemistry, Ural Division of the Russian Academy of Sciences, Yekaterinburg, Russian Federation
Author Keywords crystal field multiplet calculations; LiNiPO4; Magnetic susceptibility; Mn and Co impurities; Néel temperature; X-ray absorption spectra
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Correspondence Address Galakhov, V.R.; M. N. Miheev Institute of Metal Physics, Ural Branch of the Russian Academy of SciencesRussian Federation; email: galakhov@ifmlrs.uran.ru
Publisher Wiley-VCH Verlag
Language of Original Document English
Abbreviated Source Title Phys. Status Solidi B Basic Res.
Source Scopus