
<div class="publication-info">
	<h3>Competitive sorption of cesium and other microelements onto iron(III) hexacyanoferrate(II) in the presence of humic acids / Polyakov E.V., Volkov I.V., Khelbnikov N.A. // Radiochemistry. - 2015. - V. 57, l. 2. - P. 161-171.</h3>
	<dl>
		<dt>ISSN:</dt><dd>10663622</dd>
		<dt>Type:</dt><dd>Article</dd>
				<dt>Abstract:</dt><dd>Experiments show that particles of iron(III) hexacyanoferrate(II) (Berlin Blue, FCFe), in contrast to those of oxyhydrates, and humic acids (HAs) in aqueous solutions have surface charges (ζ-potential) of the same sign. Therefore, contact coagulation and coarsening of FCFe particles in HA solutions are impossible (in contrast, e.g., to dicalcium silicate). HA molecules are capable of dimerization; therefore, the microelements (Cs, Sr, Co, Mn, Fe, Zr, Th, U) in humate solutions form complexes with HA monomer and dimers. It is demonstrated by the example of Cs(I) sorption from humate solutions that the monomeric and dimeric complexes of microelements exhibit different sorption affinity (K<inf>d</inf>) for FCFe. Complexes of microelements with HA are kinetically inert and interact with the FCFe sorbent independently of each other. Therefore, it is possible to estimate separately the contribution of each form to the total sorption of the microelement. Except Cs(I), Ce(III), and Th(IV), the microelements under consideration in HA solutions have K<inf>d</inf> by orders of magnitude higher than in HA-free solutions. Thus, the FCFe-HA system is capable of binding microelements in the form of humate complexes and of fixing these complexes on the FCFe surface. This phenomenon can be used for efficient decontamination of materials from artificial radionuclides. © 2015 Pleiades Publishing, Inc.</dd>
		<dt>Author keywords:</dt><dd>hexacyanoferrate; humic acids; microelements; radionuclides; sorption</dd>
		<dt>Index keywords:</dt><dd>нет данных</dd>
		<dt>DOI:</dt><dd>10.1134/S1066362215020083</dd>
		<dt>Смотреть в Scopus:</dt>
			<dd>
								<a href="https://www.scopus.com/inward/record.uri?eid=2-s2.0-84928572596&doi=10.1134%2fS1066362215020083&partnerID=40&md5=eede9abcff9515f1272893167a791f1c" target="_blank">https://www.scopus.com/inward/record.uri?eid=2-s2.0-84928572596&amp;doi=10.1134%2fS1066362215020083&amp;partnerID=40&amp;md5=eede9abcff9515f1272893167a791f1c</a>
							</dd>

		<dt>Соавторы в МНС:</dt>
		<dd>
		&mdash;		</dd>

				<dt>Другие поля</dt>
		<dd>
			<table class="v-table">
			<thead>
				<tr>
					<td class="w8 gar">Поле</td>
					<td>Значение</td>
				</tr>
			</thead>
			<tbody>
								<tr>
						<td class="gar">Link</td>
						<td>https://www.scopus.com/inward/record.uri?eid=2-s2.0-84928572596&doi=10.1134%2fS1066362215020083&partnerID=40&md5=eede9abcff9515f1272893167a791f1c</td>
					</tr>
										<tr>
						<td class="gar">Affiliations</td>
						<td>Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, Russian Federation</td>
					</tr>
										<tr>
						<td class="gar">Author Keywords</td>
						<td>hexacyanoferrate; humic acids; microelements; radionuclides; sorption</td>
					</tr>
										<tr>
						<td class="gar">Funding Details</td>
						<td>RFBR, Russian Foundation for Basic Research</td>
					</tr>
										<tr>
						<td class="gar">References</td>
						<td>Alexakhin, R.M., Sanzharova, N.I., Fesenko, S.V., (2007) Health Phys., 93, pp. 418-426. , 1:CAS:528:DC%2BD2sXhtFeisrvI; Gombert, D., Global nuclear energy partnership waste treatment baseline 235th ACS Nat. Meet., New Orleans, LA (The United States), 2008, , Abstracts of Papers, NUCL-126; Michalik, B., (2009) J. Environ. Monit., 11, pp. 1825-1833. , 1:CAS:528:DC%2BD1MXht1ags7jO; Zakrzewska-Trznadel, G., (2013) Desalination, 321, pp. 119-130. , 1:CAS:528:DC%2BC3sXktlGmsbY%3D; Moskvin, A.V., (2004) Novyi Spravochnik Khimika i Tekhnologa (New Handbook for a Chemist and a Technologist), 11. , Professional, section 11; Ampelogova, N.I., Simanovskii, Yu.M., Trapeznikov, A.A., (1982) Dezaktivatsiya v Yadernoi Energetike (Decontamination in Nuclear Power Engineering), , Moscow: Energoatomizdat; Kuznetsov, Yu.V., Shchebetkovskii, V.N., Trusov, A.G., (1974) Osnovy Ohistki Vody ot Radioaktivnykh Zagryaznenii (Principles of Water Treatment to Remove Radioactive Contaminants), , Moscow: Atomizdat; Shadrin, A.Yu., (2007) Tr. Radievogo Inst. Im. V.G. Khlopina, 12, pp. 20-43; Inokuma, S., Sakaizawa, T., Funaki, T., (2003) Tetrahedron, 59, pp. 8183-8190. , 1:CAS:528:DC%2BD3sXnsVKktLk%3D; Moyer, B.A., Birdwell, J.F., Bonnesen, P.V., Delmau, L.H., (2005) Macrocylic Chemistry: Current Trends and Future Perspective, , Gloe, K., Ed., Netherlands: Springer; Samuleev, P.V., Andrews, W.S., Creber, K.A.M., (2013) J. Radioanal. Nucl. Chem., 296, pp. 811-815. , 1:CAS:528:DC%2BC3sXmtFShtrs%3D; Nuclear Radiation Decontamination Solutions for Emergency and First Responders, , http://www.raddecon.com/index.htm; Polyakov, E.V., (2012) Sed'maya Rossiiskaya Konferentsiya po Radiokhimii "Radiokhimiya-2012" (Seventh Russian Conf. on Radiochemistry "Radiochemistry-2012"), pp. 343-344. , Abstracts of Papers, Dimitrovgrad: VDV PAK; Platonov, V.V., Kalmykov, S.N., Tananaev, I.G., Myasoedov, B.F., (2012) Sed'maya Rossiiskaya Konferentsiya po Radiokhimii "Radiokhimiya-2012" (Seventh Russian Conf. on Radiochemistry "Radiochemistry-2012"), p. C. 342. , Abstracts of Papers, Dimitrovgrad: VDV PAK; Perminova, I.V., (2000), Doctoral (Chem.) Dissertation, Moscow: Moscow State Univ; Armon, R., Zolkov, Ch., Laor, Y., (2000) J. Sol-Gel Sci. Technol., 19, pp. 95-100. , 1:CAS:528:DC%2BD3MXotVyquw%3D%3D; Davis, C.J., Eschenazi, E., Papadopulos, K.D., (2000) Colloid Polym. Sci., 280, pp. 52-58; Bergelin, A., (2001) The Acid-base Properties and Aggregation of Humic Materials, , Dissertation, Stockholm (Sweden): Int. Royal Inst. of Technology; Polyakov, E.V., Il'ves, G.N., Surikov, V.T., (2000) Radiochemistry, 42 (5), pp. 472-475. , 1:CAS:528:DC%2BD3MXlvFOqtA%3D%3D; Polyakov, E.V., Volkov, I.V., Surikov, V.T., Perelyaeva, L.A., (2010) J. Radioanal. Nucl. Chem., 286, pp. 707-711. , 1:CAS:528:DC%2BC3cXhsFaqsLzI; Volkov, I.V., Polyakov, E.V., Khlebnikov, N.A., Barysheva, N.M., (2013) Radiochemistry, 55 (5), pp. 505-510. , 1:CAS:528:DC%2BC3sXhs1WitbnI; Remez, V.P., Zheltonozhko, E.V., (1997) Radioprot. Coll., 32, p. 59; Baskakov, B.M., Aidin, A.I., Babenko, A.I., (1989) Podgotovka Podrazdelenii k Zashchite ot Yadernogo, Khimicheskogo, Bakteriologicheskogo (Biologicheskogo) i zazhigatel'nogo Oruzhiya Protivnika (Preparation of Army Units to Protection from Nuclear, Chemical, Bacteriological (Biological), and Incendiary Weapons of the Enemy), , Bukhtoyarov, V.I., Ed., Moscow: Voenizdat; Egorov, Yu.V., (1975) Statika Sorbtsii Mikrokomponentov Oksigidratami (Statics of Microcomponent Sorption by Oxyhydrates), , Moscow: Atomizdat; Polyakov, E.V., (2003) Reaktsii Ionno-kolloidnykh Form Mikrokomponentov i Radionuklidov v Vodnykh Rastvorakh (Reactions of Ionic and Colloidal Species of Microcomponents and Radionuclides in Aqueous Solutions), , Yekaterinburg: Inst. Khimii Tverdogo Tela Ural'sk. Otdel. Ross. Akad. Nauk; Polyakov, E.V., Egorov, Yu.V., Panfilova, L.V., (1994) Radiokhimiya, 36 (1), p. 29. , 1:CAS:528:DyaK2cXls1Clu7c%3D; Cremers, A., Elsen, A., De Preter, P., Maes, A., (1988) Nature, 335, pp. 247-249. , 1:CAS:528:DyaL1cXls12gur4%3D; Sanzharova, N.I., Sysoeva, A.A., Isamov, N.N., (2005) Ross. Khim. Zh., 49 (3), pp. 26-34. , 1:CAS:528:DC%2BD2MXhtVSrsbvE; Stepina, I.A., Maslova, K.M., Popov, V.E., (2013) Radiochemistry, 55 (3), pp. 305-309. , 1:CAS:528:DC%2BC3sXptVWjtr0%3D; Polyakov, E.V., (2007) Radiochemistry, 49 (4), pp. 432-438. , 1:CAS:528:DC%2BD2sXhtVylurjI; Polyakov, E.V., Egorov, Yu.V., (2003) Russ. Chem. Rev., 72 (11), p. 985. , 1:CAS:528:DC%2BD2cXislSmsr0%3D; Paulenová, A., Rajec, P., Zemberyová, M., (2000) J. Radioanal. Nucl. Chem., 246, pp. 623-628; Stamberg, K., Benes, P., Mizera, J., (2003) J. Radioanal. Nucl. Chem., 258, pp. 329-345. , 1:CAS:528:DC%2BD3sXot1CksrY%3D; Nenakhov, D.V., Kotov, V.V., Stekol'nikov, K.E., (2009) Sorbts. Khromatogr. Prots., 9, pp. 301-307; Helfferich, F., (1959) Ionenaustauscher, , Weinheim: Chemie; Tananaev, I.V., (1971) Khimiya Ferrotsianidov (Chemistry of Ferrocyanides), , Moscow: Nauka; Polyakov, E.V., Denisova, T.A., Maksimova, L.G., (2000) Russ. J. Inorg. Chem., 45 (2), pp. 276-282; Polyakov, E.V., Khlebnikov, N.A., Surikov, V.T., (2009) Radioprotection, 44 (5), pp. 209-215; Polyakov, E.V., Betenekov, N.D., (1988) Kinet. Katal., 29 (3), pp. 648-652; Wauters, J., Elsen, A., Cremers, A., (1996) Appl. Geochem., 11, pp. 601-603. , 1:CAS:528:DyaK28XmtVSgurs%3D; Kossakowski, S., Dziura, A., Grosicki, A., (1991) Isot. Environ. Health Stud., 7, pp. 30-33; Samuleev, P.V., Andrews, W.S., Creber, K.A.M., (2013) J. Radioanal. Nucl. Chem., 296, pp. 811-815. , 1:CAS:528:DC%2BC3sXmtFShtrs%3D</td>
					</tr>
										<tr>
						<td class="gar">Correspondence Address</td>
						<td>Polyakov, E.V.; Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 91, Russian Federation</td>
					</tr>
										<tr>
						<td class="gar">Publisher</td>
						<td>Maik Nauka Publishing / Springer SBM</td>
					</tr>
										<tr>
						<td class="gar">CODEN</td>
						<td>RDIOE</td>
					</tr>
										<tr>
						<td class="gar">Language of Original Document</td>
						<td>English</td>
					</tr>
										<tr>
						<td class="gar">Abbreviated Source Title</td>
						<td>Radiochemistry</td>
					</tr>
										<tr>
						<td class="gar">Source</td>
						<td>Scopus</td>
					</tr>
								</tbody>
			</table>
		</dd>
			</dl>

</div>
Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84928572596&doi=10.1134%2fS1066362215020083&partnerID=40&md5=eede9abcff9515f1272893167a791f1c
Affiliations	Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, Russian Federation
Author Keywords	hexacyanoferrate; humic acids; microelements; radionuclides; sorption
Funding Details	RFBR, Russian Foundation for Basic Research
References	Alexakhin, R.M., Sanzharova, N.I., Fesenko, S.V., (2007) Health Phys., 93, pp. 418-426. , 1:CAS:528:DC%2BD2sXhtFeisrvI; Gombert, D., Global nuclear energy partnership waste treatment baseline 235th ACS Nat. Meet., New Orleans, LA (The United States), 2008, , Abstracts of Papers, NUCL-126; Michalik, B., (2009) J. Environ. Monit., 11, pp. 1825-1833. , 1:CAS:528:DC%2BD1MXht1ags7jO; Zakrzewska-Trznadel, G., (2013) Desalination, 321, pp. 119-130. , 1:CAS:528:DC%2BC3sXktlGmsbY%3D; Moskvin, A.V., (2004) Novyi Spravochnik Khimika i Tekhnologa (New Handbook for a Chemist and a Technologist), 11. , Professional, section 11; Ampelogova, N.I., Simanovskii, Yu.M., Trapeznikov, A.A., (1982) Dezaktivatsiya v Yadernoi Energetike (Decontamination in Nuclear Power Engineering), , Moscow: Energoatomizdat; Kuznetsov, Yu.V., Shchebetkovskii, V.N., Trusov, A.G., (1974) Osnovy Ohistki Vody ot Radioaktivnykh Zagryaznenii (Principles of Water Treatment to Remove Radioactive Contaminants), , Moscow: Atomizdat; Shadrin, A.Yu., (2007) Tr. Radievogo Inst. Im. V.G. Khlopina, 12, pp. 20-43; Inokuma, S., Sakaizawa, T., Funaki, T., (2003) Tetrahedron, 59, pp. 8183-8190. , 1:CAS:528:DC%2BD3sXnsVKktLk%3D; Moyer, B.A., Birdwell, J.F., Bonnesen, P.V., Delmau, L.H., (2005) Macrocylic Chemistry: Current Trends and Future Perspective, , Gloe, K., Ed., Netherlands: Springer; Samuleev, P.V., Andrews, W.S., Creber, K.A.M., (2013) J. Radioanal. Nucl. Chem., 296, pp. 811-815. , 1:CAS:528:DC%2BC3sXmtFShtrs%3D; Nuclear Radiation Decontamination Solutions for Emergency and First Responders, , http://www.raddecon.com/index.htm; Polyakov, E.V., (2012) Sed'maya Rossiiskaya Konferentsiya po Radiokhimii "Radiokhimiya-2012" (Seventh Russian Conf. on Radiochemistry "Radiochemistry-2012"), pp. 343-344. , Abstracts of Papers, Dimitrovgrad: VDV PAK; Platonov, V.V., Kalmykov, S.N., Tananaev, I.G., Myasoedov, B.F., (2012) Sed'maya Rossiiskaya Konferentsiya po Radiokhimii "Radiokhimiya-2012" (Seventh Russian Conf. on Radiochemistry "Radiochemistry-2012"), p. C. 342. , Abstracts of Papers, Dimitrovgrad: VDV PAK; Perminova, I.V., (2000), Doctoral (Chem.) Dissertation, Moscow: Moscow State Univ; Armon, R., Zolkov, Ch., Laor, Y., (2000) J. Sol-Gel Sci. Technol., 19, pp. 95-100. , 1:CAS:528:DC%2BD3MXotVyquw%3D%3D; Davis, C.J., Eschenazi, E., Papadopulos, K.D., (2000) Colloid Polym. Sci., 280, pp. 52-58; Bergelin, A., (2001) The Acid-base Properties and Aggregation of Humic Materials, , Dissertation, Stockholm (Sweden): Int. Royal Inst. of Technology; Polyakov, E.V., Il'ves, G.N., Surikov, V.T., (2000) Radiochemistry, 42 (5), pp. 472-475. , 1:CAS:528:DC%2BD3MXlvFOqtA%3D%3D; Polyakov, E.V., Volkov, I.V., Surikov, V.T., Perelyaeva, L.A., (2010) J. Radioanal. Nucl. Chem., 286, pp. 707-711. , 1:CAS:528:DC%2BC3cXhsFaqsLzI; Volkov, I.V., Polyakov, E.V., Khlebnikov, N.A., Barysheva, N.M., (2013) Radiochemistry, 55 (5), pp. 505-510. , 1:CAS:528:DC%2BC3sXhs1WitbnI; Remez, V.P., Zheltonozhko, E.V., (1997) Radioprot. Coll., 32, p. 59; Baskakov, B.M., Aidin, A.I., Babenko, A.I., (1989) Podgotovka Podrazdelenii k Zashchite ot Yadernogo, Khimicheskogo, Bakteriologicheskogo (Biologicheskogo) i zazhigatel'nogo Oruzhiya Protivnika (Preparation of Army Units to Protection from Nuclear, Chemical, Bacteriological (Biological), and Incendiary Weapons of the Enemy), , Bukhtoyarov, V.I., Ed., Moscow: Voenizdat; Egorov, Yu.V., (1975) Statika Sorbtsii Mikrokomponentov Oksigidratami (Statics of Microcomponent Sorption by Oxyhydrates), , Moscow: Atomizdat; Polyakov, E.V., (2003) Reaktsii Ionno-kolloidnykh Form Mikrokomponentov i Radionuklidov v Vodnykh Rastvorakh (Reactions of Ionic and Colloidal Species of Microcomponents and Radionuclides in Aqueous Solutions), , Yekaterinburg: Inst. Khimii Tverdogo Tela Ural'sk. Otdel. Ross. Akad. Nauk; Polyakov, E.V., Egorov, Yu.V., Panfilova, L.V., (1994) Radiokhimiya, 36 (1), p. 29. , 1:CAS:528:DyaK2cXls1Clu7c%3D; Cremers, A., Elsen, A., De Preter, P., Maes, A., (1988) Nature, 335, pp. 247-249. , 1:CAS:528:DyaL1cXls12gur4%3D; Sanzharova, N.I., Sysoeva, A.A., Isamov, N.N., (2005) Ross. Khim. Zh., 49 (3), pp. 26-34. , 1:CAS:528:DC%2BD2MXhtVSrsbvE; Stepina, I.A., Maslova, K.M., Popov, V.E., (2013) Radiochemistry, 55 (3), pp. 305-309. , 1:CAS:528:DC%2BC3sXptVWjtr0%3D; Polyakov, E.V., (2007) Radiochemistry, 49 (4), pp. 432-438. , 1:CAS:528:DC%2BD2sXhtVylurjI; Polyakov, E.V., Egorov, Yu.V., (2003) Russ. Chem. Rev., 72 (11), p. 985. , 1:CAS:528:DC%2BD2cXislSmsr0%3D; Paulenová, A., Rajec, P., Zemberyová, M., (2000) J. Radioanal. Nucl. Chem., 246, pp. 623-628; Stamberg, K., Benes, P., Mizera, J., (2003) J. Radioanal. Nucl. Chem., 258, pp. 329-345. , 1:CAS:528:DC%2BD3sXot1CksrY%3D; Nenakhov, D.V., Kotov, V.V., Stekol'nikov, K.E., (2009) Sorbts. Khromatogr. Prots., 9, pp. 301-307; Helfferich, F., (1959) Ionenaustauscher, , Weinheim: Chemie; Tananaev, I.V., (1971) Khimiya Ferrotsianidov (Chemistry of Ferrocyanides), , Moscow: Nauka; Polyakov, E.V., Denisova, T.A., Maksimova, L.G., (2000) Russ. J. Inorg. Chem., 45 (2), pp. 276-282; Polyakov, E.V., Khlebnikov, N.A., Surikov, V.T., (2009) Radioprotection, 44 (5), pp. 209-215; Polyakov, E.V., Betenekov, N.D., (1988) Kinet. Katal., 29 (3), pp. 648-652; Wauters, J., Elsen, A., Cremers, A., (1996) Appl. Geochem., 11, pp. 601-603. , 1:CAS:528:DyaK28XmtVSgurs%3D; Kossakowski, S., Dziura, A., Grosicki, A., (1991) Isot. Environ. Health Stud., 7, pp. 30-33; Samuleev, P.V., Andrews, W.S., Creber, K.A.M., (2013) J. Radioanal. Nucl. Chem., 296, pp. 811-815. , 1:CAS:528:DC%2BC3sXmtFShtrs%3D
Correspondence Address	Polyakov, E.V.; Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 91, Russian Federation
Publisher	Maik Nauka Publishing / Springer SBM
CODEN	RDIOE
Language of Original Document	English
Abbreviated Source Title	Radiochemistry
Source	Scopus