Solvent-Free Reaction of 1,2,4-Triazine-5-carbonitriles with 4-(Cyclohex-1-en-1-yl)morpholine. Unexpected Decyanation in Addition to Classical Aza- Diels-Alder Reaction / Kopchuk D. S.,Khasanov A. F.,Chepchugov N. V.,Kovalev I. S.,Zyryanov G. V.,Rusinov V. L.,Chupakhin O. N. // RUSSIAN JOURNAL OF ORGANIC CHEMISTRY. - 2017. - V. 53, l. 1. - P. 99-102.

ISSN/EISSN:

1070-4280 / 1608-3393

Type:

Article

Abstract:

The reaction of 1,2,4-triazine-5-carbonitriles with 4-(cyclohex-1-en-1-yl) morpholine under solvent-free conditions has been found to follow two pathways: aza-Diels-Alder reaction and unexpected decyanation of the initial nitriles. The scope of the revealed decyanation reaction has been roughly estimated.

Author keywords:

SUBSTITUTED PYRIDINES; 1,2,4-TRIAZINES; DERIVATIVES; COMPLEXES; ANALOGS

DOI:

10.1134/S1070428017010183

Web of Science ID:

ISI:000396525200018

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JAN
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3393
Keywords-Plus	SUBSTITUTED PYRIDINES; 1,2,4-TRIAZINES; DERIVATIVES; COMPLEXES; ANALOGS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	gvzyryanov@gmail.com
Funding-Acknowledgement	Russian Science Foundation {[}16-4302-020]; Council for Grants at the President of the Russian Federation {[}MK-644.2017.3]; Government of the Russian Federation {[}02.A03.21.0006]
Funding-Text	This study was performed under financial support by the Russian Science Foundation (project no. 16-4302-020), by the Council for Grants at the President of the Russian Federation (project no. MK-644.2017.3), and by the Government of the Russian Federation (program no. 211, contract no. 02.A03.21.0006).
Number-of-Cited-References	23
Usage-Count-Last-180-days	5
Usage-Count-Since-2013	5
Journal-ISO	Russ. J. Organ. Chem.
Doc-Delivery-Number	EO2KK