Microwave-assisted synthesis of 4-(2,2 `-bithiophen-5-yl)-5-phenylpyrimidine derivatives as sensors for detection of nitroaromatic explosives / Verbitskiy Egor V.,Cheprakova Ekaterina M.,Baranova Anna A.,Khokhlov Konstantin O.,Lugovik Kseniya I.,Rusinov Gennady L.,Chupakhin Oleg N.,Charushin Valery N. // CHEMISTRY OF HETEROCYCLIC COMPOUNDS. - 2016. - V. 52, l. 11. - P. 904-909.

ISSN/EISSN:

0009-3122 / 1573-8353

Type:

Article

Abstract:

A reaction sequence involving microwave-assisted Suzuki cross-coupling steps and bromination with N-bromosuccinimide was used to synthesize 4-\{4-{[}4',5'-bis(4-diphenylaminophenyl)-3'-hexyl-2,2'-bithiophen-5-yl] pyrimidin-5-yl\}benzonitrile. The optical properties of the obtained compound were studied to evaluate it for possible applications as a sensor of nitroaromatic compounds in acetonitrile solutions and gas phase.

Author keywords:

pyrimidine; triphenylamine; fluorescence quenching; nitroaromatic explosives; sensors NUCLEOPHILIC AROMATIC-SUBSTITUTION; PICRIC ACID DETECTION; AQUEOUS-MEDIA; HYDROGEN; SYSTEMS

DOI:

10.1007/s10593-017-1984-1

Web of Science ID:

ISI:000392938800007

Соавторы в МНС:

Другие поля

Поле	Значение
Month	NOV
Publisher	SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013 USA
Language	English
EISSN	1573-8353
Keywords-Plus	NUCLEOPHILIC AROMATIC-SUBSTITUTION; PICRIC ACID DETECTION; AQUEOUS-MEDIA; HYDROGEN; SYSTEMS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	Verbitsky@ios.uran.ru
Funding-Acknowledgement	Russian Science Foundation {[}16-13-10435]
Funding-Text	This work was supported by a grant from the Russian Science Foundation (project No. 16-13-10435).
Number-of-Cited-References	32
Usage-Count-Last-180-days	4
Usage-Count-Since-2013	6
Journal-ISO	Chem. Heterocycl. Compds.
Doc-Delivery-Number	EJ0ZC