Electrode Potentials of Tungsten in Fused Alkali Chlorides / Ivanov A. B.,Volkovich V. A.,Poskryakov D. A.,Vasin B. D.,Griffiths T. R. // . - 2016. - V. 1767, l. .

ISSN/EISSN:
0094-243X / нет данных
Type:
Proceedings Paper
Abstract:
Anodic dissolution of tungsten was studied at 823-1173 K in the melts based on NaCl-CsCl, NaCl-KCl-CsCl and LiCl-KCl-CsCl eutectic mixtures. The process results in the formation of W(IV) ions. Prolonged contact with silica results in oxidation W(IV) ions and decreasing tungsten concentration in the electrolyte due to formation of volatile higher oxidation state chloro-and oxychloro-species. Tungsten electrode potentials were measured in NaCl-CsCl and NaCl-KCl-CsCl based melts using potentiometry.
Author keywords:
нет данных
DOI:
10.1063/1.4962594
Web of Science ID:
ISI:000392693900010
Соавторы в МНС:
Другие поля
Поле Значение
Editor Rempel, AA and Volkovich, VA
Booktitle PHYSICS, TECHNOLOGIES AND INNOVATION (PTI-2016)
Series AIP Conference Proceedings
Note 3rd International Young Researchers Conference - Physics, Technologies and Innovation (PTI), Ekaterinburg, RUSSIA, MAY 16-20, 2016
Organization Ural Fed Univ, Inst Phys \& Technol
Publisher AMER INST PHYSICS
Address 2 HUNTINGTON QUADRANGLE, STE 1NO1, MELVILLE, NY 11747-4501 USA
Language English
Article-Number 020010
ISBN 978-0-7354-1425-9
Research-Areas Physics
Web-of-Science-Categories Physics, Applied; Physics, Multidisciplinary
Author-Email chuvasch@yandex.ru v.a.volkovich@urfu.ru t.r.griffiths@gmail.com
ResearcherID-Numbers Volkovich, Vladimir/K-8339-2012 Ivanov, Alexander/F-7655-2017
ORCID-Numbers Volkovich, Vladimir/0000-0003-4438-1194
Funding-Acknowledgement Ministry of Education and Science of Russian Federation {[}N976.42G.041/14]
Funding-Text The authors are grateful to the Ministry of Education and Science of Russian Federation for the financial support (under Agreement N976.42G.041/14).
Number-of-Cited-References 3
Usage-Count-Last-180-days 2
Usage-Count-Since-2013 2
Doc-Delivery-Number BG8SP