Effect of protonation on the formation of microcomposition structure of materials / Bamburov VG,Sergeyev MA,Semukhin BS,Shveikin GP // INTERNATIONAL JOURNAL OF HYDROGEN ENERGY. - 2000. - V. 25, l. 4. - P. 351-356.

ISSN/EISSN:

0360-3199 / нет данных

Type:

Article

Abstract:

The results on protonation in solutions and melts of salts and acids, as well as structural changes associated with the formation of microcomposition (MC) structure of materials are presented, The associated protonation is a necessary condition for proton separation of structural units (PSU) in MC structure model. The shape and size of PSU in simple substances and compounds and their variation in phase transition have been determined with the use of modified formula of cinematic diffraction theory applied to minimal scattering volumes. The possibilities of variation in PSU block size, interblock isotope exchange and proton-ionic microalloying by single and two valence ions have been demonstrated with regard to protonation regimes. A conclusion has been made that high content of interblock protons causes mechanical/chemical splitting in crystals. (C) 2000 Published by Elsevier Science Ltd on behalf of the International Association for Hydrogen Energy, All rights reserved.

Author keywords:

нет данных

DOI:

10.1016/S0360-3199(99)00034-8

Web of Science ID:

ISI:000085214700007

Соавторы в МНС:

Другие поля

Поле	Значение
Month	APR
Publisher	PERGAMON-ELSEVIER SCIENCE LTD
Address	THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Language	English
Research-Areas	Chemistry; Electrochemistry; Energy \& Fuels
Web-of-Science-Categories	Chemistry, Physical; Electrochemistry; Energy \& Fuels
ResearcherID-Numbers	Bamburov, Vitaliy/J-3241-2017
Number-of-Cited-References	23
Usage-Count-Since-2013	3
Journal-ISO	Int. J. Hydrog. Energy
Doc-Delivery-Number	282JK