Oxygen isotope exchange and diffusion in LnBaCo2O6 − δ (Ln = Pr, Sm, Gd) with double perovskite structure / Ananyev M.V., Eremin V.A., Tsvetkov D.S., Porotnikova N.M., Farlenkov A.S., Zuev A.Y., Fetisov A.V., Kurumchin E.K. // Solid State Ionics. - 2017. - V. 304, l. . - P. 96-106.

ISSN:

01672738

Type:

Article

Abstract:

The interaction of oxygen in the gas phase with double perovskites LnBaCo2O6 − δ (Ln = Pr, Sm, Gd) was studied by the isotope exchange method with gas phase equilibration in the temperature range of 600–850 °C and the oxygen pressure range of 1.3 · 10− 3–6.6 · 10− 2 atm. The oxygen nonstoichiometry of the oxides was determined by means of the thermogravimetric analysis as a function of oxygen partial pressure and temperature in the ranges − 3 ≤ log(Po2/atm) ≤ − 0.68 and 600 ≤ T, °C ≤ 850, respectively. The influence of the oxygen nonstoichiometry on the heterogeneous exchange rate and the oxygen tracer diffusion coefficient was discussed. The rate-determining stage of the oxygen surface exchange kinetics for PrBaCo2O6 − δ was found to be different in comparison with SmBaCo2O6 − δ and GdBaCo2O6 − δ. The possible reasons of this observation were considered. © 2017

Author keywords:

Double perovskite; Gas-phase analysis; Oxygen surface exchange; Oxygen tracer diffusion; Solid oxide fuel cells

Index keywords:

Diffusion; Diffusion in gases; Gas fuel analysis; Gases; Isotopes; Perovskite; Solid oxide fuel cells (SOFC); Thermal logging; Thermogravimetric analysis; Double perovskite structures; Double perovski

DOI:

10.1016/j.ssi.2017.03.022

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https://www.scopus.com/inward/record.uri?eid=2-s2.0-85017154050&doi=10.1016%2fj.ssi.2017.03.022&partnerID=40&md5=ab27216d07a8e147635a19459f868f7f

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Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-85017154050&doi=10.1016%2fj.ssi.2017.03.022&partnerID=40&md5=ab27216d07a8e147635a19459f868f7f
Affiliations	Institute of High Temperature Electrochemistry, UB RAS, Yekaterinburg, Russian Federation; Ural Federal University named after the first President of Russia B. N. Yeltsin, Yekaterinburg, Russian Federation; Institute of Metallurgy, UB RAS, Yekaterinburg, Russian Federation
Author Keywords	Double perovskite; Gas-phase analysis; Oxygen surface exchange; Oxygen tracer diffusion; Solid oxide fuel cells
Funding Details	16-13-00053, RSF, Russian Science Foundation
Funding Text	The facilities of the shared access centers “Composition of Compounds” of IHTE UB RAS and “Ural-M” of IMET UB RAS were used in this work. The authors thank B.D. Antonov for XRD measurements, N.G. Molchanova for ICP-AES analysis and A.A. Pankratov for SEM–EDX analysis. This work is partly supported by the Russian Foundation of Basic Research (Project No. 14-29-04009) and Russian Science Foundation (Project No. 16-13-00053); supported by Act 211 of Government of the Russian Federation, agreement № 02.A03.21.0006 and grants of the President of Russian Federation 2015–2017 (No. СП-1572.2015.1, СП-1663.2015.1).
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Correspondence Address	Ananyev, M.V.; Institute of High Temperature Electrochemistry, UB RASRussian Federation; email: amv@ihte.uran.ru
Publisher	Elsevier B.V.
CODEN	SSIOD
Language of Original Document	English
Abbreviated Source Title	Solid State Ionics
Source	Scopus