Magnetic properties of YFeO3 nanocrystals obtained by different soft-chemical methods / Popkov V.I., Almjasheva O.V., Semenova A.S., Kellerman D.G., Nevedomskiy V.N., Gusarov V.V. // Journal of Materials Science: Materials in Electronics. - 2017. - V. 28, l. 10. - P. 7163-7170.

ISSN:
09574522
Type:
Article
Abstract:
In recent years materials based on nanocrystalline YFeO3 draw considerable research interest as the basis of innovative magnetic and magneto-optical devices. However, the size and the morphology of the nanocrystals are well-known to have a drastic influence on its functional properties. In present work, the effect of size and morphological features on magnetic properties of YFeO3 nanocrystals is investigated. Yttrium orthoferrite nanocrystals were synthesized via four soft-chemical routes—glycine-nitrate synthesis (GNS), thermal treatment of GNS products, hydrothermal and thermal treatments of co-precipitated hydroxides. Obtained samples were characterized by powder X-ray diffraction (PXRD), transmission electron microscopy (TEM) and vibrational magnetometry (VM). It was shown that synthesized compositions correspond to single-phase nanocrystals of orthorhombic YFeO3 with different morphology (isometric, plate-like, rod-shaped) and average crystallite sizes ranging from 29 ± 3 to 58 ± 6 nm depending on synthesis route. Basic magnetic characteristics of its nanocrystals—residual magnetization (Mres) and coercivity (Hcoerc)—also show strong dependence on YFeO3 synthesis route, average crystallite size and its morphology and vary in the ranges 70–273 emu/mol and 1.8–21.0 kOe correspondingly. It was found that nanocrystals with isometric morphology obtained by different synthesis routes demonstrate simultaneous increase of residual magnetization and decrease of coercivity with growth of crystallite size. However, it was also found that as morphology becomes nonisometric (plate-like and rod-shaped) these trends are not observed anymore and magnetic behavior of YFeO3 is defined by interactions of weak-ferromagnetic and antiferromagnetic orderings in nanocrystals along its anisotropic directions. © 2017, Springer Science+Business Media New York.
Author keywords:
Index keywords:
Amino acids; Coercive force; Crystallite size; Heat treatment; High resolution transmission electron microscopy; Hydrothermal synthesis; Magnetic properties; Magnetism; Magnetization; Morphology; Nano
DOI:
10.1007/s10854-017-6676-1
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Affiliations Department of Physical Chemistry, Saint-Petersburg State Institute of Technology (Technical University), Saint-Petersburg, Russian Federation; Laboratory of New Inorganic Materials, Ioffe Physical-Technical Institute of RAS, Saint-Petersburg, Russian Federation; Department of Physical Chemistry, Saint-Petersburg State Electrotechnical University, Saint-Petersburg, Russian Federation; Laboratory of Quantum Chemistry and Spectroscopy, Institute of Solid State Chemistry of the Ural Branch of RAS, Ekaterinburg, Russian Federation; Laboratory of Characterization of Materials and Solid State Electronics Structures, Ioffe Physical-Technical Institute of RAS, Saint-Petersburg, Russian Federation
Funding Details 16-33-10252, RSF, Russian Science Foundation
References Kodama, R.H., Magnetic nanoparticles (1999) J. Magn. Magn. Mater, 200, pp. 359-372; Tretyakov, Y.D., Development of inorganic chemistry as a fundamental for the design of new generations of functional materials (2004) Russ. Chem. Rev, 73, pp. 831-846; Gubin, S.P., Koksharov, Y.A., Khomutov, G.B., Yurkov, G.Y., Magnetic nanoparticles: preparation, structure and properties (2005) Russ. Chem. Rev, 74, pp. 489-520; Rempel, A.A., Nanotechnologies. Properties and applications of nanostructured materials (2007) Russ. Chem. Rev, 76, pp. 435-461; Pankhurst, Q.A., Connoly, J., Jones, S.K., Dobson, J., Applications of magnetic nanoparticles in biomedicine (2003) J. Phys. D Appl. Phys, 36, pp. 167-181; Gonzalez-Melendi, P., Fernandez-Pacheco, R., Coronado, M.J., Corredor, E., Testillano, P.S., Risueno, M.C., Nanoparticles as smart treatment-delivery systems in plants: assessment of different techniques of microscopy for their visualization in plant tissues (2008) Ann. Bot, 101, pp. 187-195; McHenry, M.E., Laughlin, D.E., Nano-scale materials development for future magnetic applications (2000) Acta Mater, 48, pp. 223-238; J. Phys. Condens Matter. 15, , http://stacks.iop.org/JPhysCM/15/R841, R. Skomski, Nanomagnetics. 841–896; George, M., Mary, A., Nair, S.S., Joy, P.A., Anantharaman, M.R., Finite size effects on the structural and magnetic properties of sol–gel synthesized NiFe2O4 powders (2006) J. Magn. Magn. Mater, 302, pp. 190-195; Park, T., Papaefthymiou, G.C., Viescas, A.J., Moodenbaugh, A.R., Wong, S.S., Size-dependent magnetic properties of nanoparticles (2007) Nano. Lett, 7, pp. 766-772; Popkov, V.I., Almjasheva, O.V., Yttrium orthoferrite YFeO3 nanopowders formation under glycine-nitrate combustion conditions (2014) Russ. J. Appl. Chem, 87, pp. 167-171; Nanocrystalline perovskite-like oxides formation in Ln2O3 - Fe2O3 - H2O (Ln = La, Gd) systems. Nanosystems 5, , http://nanojournal.ifmo.ru/en/articles-2/volume5/5-6/chemistry/paper14/, E.A. Tugova, O.N. Karpov, 854–860; Tac, D.V., Mittova, V.O., Mittova, I.Y., Influence of lanthanum content and annealing temperature on the size and magnetic properties of sol–gel derived Y1−xLaxFeO3 nanocrystals (2011) Inorg. Mater, 47, pp. 590-595; Mathur, S., Veith, M., Rapalaviciute, R., Shen, H., Goya, G.F., Filho, W.L.M., Molecule derived synthesis of nanocrystalline YFeO3 and investigations on its weak ferromagnetic behavior (2004) Chem. Mater, 16, pp. 1906-1913; (2014) Nanosystems 5, , http://nanojournal.ifmo.ru/en/articles-2/volume5/5-5/chemistry/paper09/, V.I. Popkov, O.V. Almjasheva, Formation mechanism of YFeO3 nanoparticles under the hydrothermal conditions. 703–708; Li, C., Soh, K.C.K., Wu, P., Formability of ABO3 perovskites (2004) J. Alloys Compd, 372, pp. 40-48; Georgiev, D.G., Krezhov, K.A., Nietz, V.V., Weak antiferromagnetism in YFeO3 and HoFeO3 (1995) Solid State Commun, 96, pp. 535-537; Shang, M., Zhang, C., Zhang, T., Yuan, L., Ge, L., Yuan, H., The multiferroic perovskite YFeO3 (2013) Appl. Phys. Lett, 102, p. 62903; Chen, Y., Yang, J., Wang, X., Feng, F., Zhang, Y., Tang, Y., Synthesis YFeO3 by salt-assisted solution combustion method and its photocatalytic activity (2014) J. Ceram. Soc. Jpn, 122, pp. 146-150; Tang, P., Sun, H., Chen, H., Cao, F., Hydrothermal processing-assisted synthesis of nanocrystalline YFeO3 and its visible-light photocatalytic activity (2012) Curr. Nanosci, 8, pp. 64-67; Hou, D., Feng, L., Zhang, J., Dong, S., Zhou, D., Lim, T.T., Preparation, characterization and performance of a novel visible light responsive spherical activated carbon-supported and Er3+:YFeO3-doped TiO2 photocatalyst (2012) J. Hazard. Mater, 199-200, pp. 301-308; Didosyan, Y.S., Hauser, H., Nicolics, J., Haberl, F., Application of orthoferrites for light spot position measurements (2000) J. Appl. Phys, 87, pp. 7079-7081; Zhou, Z., Guo, L., Yang, H., Liu, Q., Ye, F., Hydrothermal synthesis and magnetic properties of multiferroic rare-earth orthoferrites (2014) J. Alloys Compd, 583, pp. 21-31; Popkov, V.I., Almjasheva, O.V., Schmidt, M.P., Izotova, S.G., Gusarov, V.V., Features of nanosized YFeO3 formation under heat treatment of glycine – nitrate combustion products (2015) Russ J. Inorg. Chem, 60, pp. 1193-1198; Popkov, V.I., Almjasheva, O.V., Schmidt, M.P., Gusarov, V.V., Formation mechanism of nanocrystalline Yttrium Orthoferrite under heat treatment of the coprecipitated hydroxides (2015) Russ. J. Gen. Chem, 85, pp. 1370-1375; Alexander, L., Klug, H., Determination of crystallite size with the X-ray spectrometer (1950) J. Appl. Phys, 21, pp. 137-142; Geller, S., Wood, E.A., Crystallographic studies of perovskite-like compounds. I. Rare earth orthoferrites and YFeO3, YCrO3, YAlO3 (1956) Acta Crystallogr, 9, pp. 563-568; Treves, D., Studies on orthoferrites at the Weizmann Institute of Science (1965) J. Appl. Phys, 36, p. 1033; White, R.L., Review of recent work on the magnetic and spectroscopic properties of the rare-earth orthoferrites (1969) J. Appl. Phys, 40, p. 1061; Dzyaloshinsky, I., A thermodynamic theory of “weak” ferromagnetism of antiferromagnetics (1958) J. Phys. Chem. Solids, 4, pp. 241-255; Lima, E., Martins, T.B., Rechenberg, H.R., Goya, G.F., Cavelius, C., Rapalaviciute, R., Numerical simulation of magnetic interactions in polycrystalline YFeO3 (2008) J. Magn. Magn. Mater, 320, pp. 622-629; Schmool, D., Keller, N., Guyot, M., Krishnan, R., Tessier, M., Evidence of very high coercive fields in orthoferrite phases of PLD grown thin films (1999) J. Magn. Magn. Mater, 195, pp. 291-298; Downie, L.J., Goff, R.J., Kockelmann, W., Forder, S.D., Parker, J.E., Morrison, F.D., Structural, magnetic and electrical properties of the hexagonal ferrites MFeO3 (M = Y, Yb, In) (2012) J. Solid State Chem, 190, pp. 52-60; Jacobs, I.S., Field-induced spin reorientation in YFeO3 and YCrO3 (1971) J. Appl. Phys, 42, p. 1631; Durbin, G.W., Johnson, C.E., Thomas, M.F., Direct observation of field-induced spin reorientation in YFeO3 by the Mossbauer effect (1975) J. Phys. C Solid State Phys, 8, pp. 3051-3057; Lütgemeier, H., Bohn, H.G., Brajczewska, M., NMR observation of the spin structure and field induced spin reorientation in YFeO3 (1980) J. Magn. Magn. Mater, 21, pp. 289-296; Zhang, W., Fang, C., Yin, W., Zeng, Y., One-step synthesis of yttrium orthoferrite nanocrystals via sol-gel auto-combustion and their structural and magnetic characteristics, Mater (2013) Chem. Phys, 137, pp. 877-883; Shen, H., Xu, J., Wu, A., Zhao, J., Shi, M., Magnetic and thermal properties of perovskite YFeO3 single crystals (2009) Mater. Sci. Eng. B Solid-State Mater. Adv. Technol, 157, pp. 77-80
Correspondence Address Popkov, V.I.; Laboratory of New Inorganic Materials, Ioffe Physical-Technical Institute of RASRussian Federation; email: vadim.i.popkov@gmail.com
Publisher Springer New York LLC
Language of Original Document English
Abbreviated Source Title J Mater Sci Mater Electron
Source Scopus