Magnetic ordering and crystal structure of LiMPO4 compounds with M = (Mn, Fe, Ni/Mn, and Ni/Co) / Urusova N.V., Semkin M.A., Lee S., Barykina Y.A., Kellerman D.G., Teplykh A.E., Pirogov A.N., Volegov A.S., Skryabin Y.N. // Ferroelectrics. - 2017. - V. 509, l. 1. - P. 74-79.

ISSN:

00150193

Type:

Article

Abstract:

We present susceptibility, X-ray and neutron diffraction data on powder orthophosphates LiMnPO4, LiFePO4, LiNi0.9Co0.1PO4, and LiNi0.9Mn0.1PO4. Dependences of structure parameters and magnetic state of these compounds on type of 3d element and content of 3d-electrons have been studied. Magnetic moment of 3d-transition ion is orientated along a-axis in LiMnPO4, along b-axis in LiFePO4, and along c-axis in both LiNi0.9Mn0.1PO4 and LiNi0.9Co0.1PO4. At low temperatures, a magnetic moment magnitude is equal to 4.0 μB in LiMnPO4 and LiFePO4 samples, while it is twice less for LiNi0.9Co0.1PO4. © 2017 Taylor & Francis Group, LLC.

Author keywords:

crystal structure; Lithium-transition metal orthophosphate; magnetic ordering; magnetization

Index keywords:

Lithium alloys; Magnetic moments; Magnetism; Magnetization; Manganese; Nickel; Transition metals; 3d electron; 3d transition; 3d-elements; Low temperatures; Magnetic state; Moment magnitudes; Structur

DOI:

10.1080/00150193.2017.1293442

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85019154216&doi=10.1080%2f00150193.2017.1293442&partnerID=40&md5=8f6ed6918978fff8edde116188990c82

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Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-85019154216&doi=10.1080%2f00150193.2017.1293442&partnerID=40&md5=8f6ed6918978fff8edde116188990c82
Affiliations	Institute of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg, Russian Federation; Neutron Science Division, Korea Atomic Energy Research Institute, Daejeon, South Korea; Institute of Solid State Chemistry UB RAS, Ekaterinburg, Russian Federation; M. N. Mikheev Institute of Metal Physics UB RAS, Ekaterinburg, Russian Federation
Author Keywords	crystal structure; Lithium-transition metal orthophosphate; magnetic ordering; magnetization
References	Eerenstein, W., Mathur, N.D., Scott, J.F., Multiferroic and magnetoelectric materials (2006) Nature, 442, pp. 759-765; Lee, S., Lee, H., Choi, Y.N., Semkin, M.A., Teplykh, A.E., Skryabin, Y.N., Li, W.-H., Pirogov, A.N., Temperature dependence of the propagation vector in Ni3-xCoxV2O8 with x=0.1 and 0.5 (2016) J Magn Magn Mater, 397, pp. 225-229; Santoro, R.P., Segal, D.J., Newnham, R.E., Magnetic properties of LiCoPO4 and LiNiPO4 (1966) J Phys Chem Solids, 27, pp. 1192-1193; Bechir, M.B., Rhaiem, A.B., Guidara, K., A.c. conductivity and dielectric study of LiNiPO4 synthesized by solid-state method (2014) Bull Mater Sci., 37, pp. 473-480; Rodriguez-Carvajal, J., Recent advances in magnetic structure determination by neutron powder diffraction (1993) Physica B, 192, pp. 55-69; Abrahams, I., Easson, K.S., Structure of lithium nickel phosphate (1993) Acta Cryst, 49, pp. 925-926; Xu, Y.N., Ching, W.Y., Chiang, Y.M., Comparative studies of the electronic structure of LiFePO4, FePO4, Li3PO4, LiMnPO4, LiCoPO4 and LiNiPO4 (2004) J Appl Phys, 95, pp. 6583-6585; Yamada, A., Takei, Y., Koizumi, H., Sonoyama, N., Kanno, R., Itoh, K., Yonemura, M., Kamiyama, T., Electrochemical, magnetic and structural investigation of the Lix(MnyFe1-y)PO4 olivine phases (2006) Chem Mater, 18, pp. 804-813; Vaknin, D., Zarestky, J.L., Rivera, J.-P., Schmid, H., Commensurate-incommensurate magnetic phase transition in magnetoelectric single crystal LiNiPO4 (2004) Phys Rev Lett, 92, p. 207201
Correspondence Address	Urusova, N.V.; Institute of Natural Sciences and Mathematics, Ural Federal UniversityRussian Federation; email: natali.urusova@mail.ru
Publisher	Taylor and Francis Inc.
CODEN	FEROA
Language of Original Document	English
Abbreviated Source Title	Ferroelectrics
Source	Scopus