Enthalpy of mixing of porous nanocluster polyoxometalates of keplerate-type Mo72Fe30 with polyvinyl alcohol and polyethylene glycol / Tonkushina M. O.,Ostroushko A. A. // RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A. - 2017. - V. 91, l. 6. - P. 1076-1079.

ISSN/EISSN:

0036-0244 / 1531-863X

Type:

Article

Abstract:

The interaction between porous spherical nanocluster polyoxometalate and water-soluble nonionic polymers (polyvinyl alcohol and polyethylene glycol) in the compositions of film is studied via calorimetry. The concentration dependences of the enthalpies of these processes are obtained using calculations based on the thermodynamic cycle.

Author keywords:

nanocluster porous spherical iron-containing polyoxometalate of keplerate type; water-soluble nonionic polymers; films; calorimetry; enthalpy of interaction BUCKYBALL STRUCTURE; MOLYBDENUM-OXIDE; POLYOXOMOLYBDATES; POLYMERS; WATER

DOI:

10.1134/S0036024417060267

Web of Science ID:

ISI:000402082000016

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JUN
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1531-863X
Keywords-Plus	BUCKYBALL STRUCTURE; MOLYBDENUM-OXIDE; POLYOXOMOLYBDATES; POLYMERS; WATER
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Physical
Author-Email	alexander.ostroushko@urfu.ru
Funding-Acknowledgement	Russian Foundation for Basic Research {[}15-03-03603]; Program for Improving the Competitiveness of Ural Federal University
Funding-Text	This work was performed as part of a State Task of the RF Ministry of Education and Science. It was supported by the Russian Foundation for Basic Research, project no. 15-03-03603; and by the Program for Improving the Competitiveness of Ural Federal University. We are grateful for A.P. Safronov for his help in calorimetric measurements.
Number-of-Cited-References	17
Usage-Count-Last-180-days	2
Usage-Count-Since-2013	2
Journal-ISO	Russ. J. Phys. Chem. A
Doc-Delivery-Number	EV9CL