Magnetic ordering and crystal structure of LiMPO4 compounds with M = (Mn, Fe, Ni/Mn, and Ni/Co) / Urusova N. V.,Semkin M. A.,Lee S.,Barykina Yu. A.,Kellerman D. G.,Teplykh A. E.,Pirogov A. N.,Volegov A. S.,Skryabin Yu. N. // FERROELECTRICS. - 2017. - V. 509, l. 1. - P. 74-79.

ISSN/EISSN:
0015-0193 / 1563-5112
Type:
Article
Abstract:
We present susceptibility, X-ray and neutron diffraction data on powder orthophosphates LiMnPO4, LiFePO4, LiNi0.9Co0.1PO4, and LiNi0.9Mn0.1PO4. Dependences of structure parameters and magnetic state of these compounds on type of 3d element and content of 3d-electrons have been studied. Magnetic moment of 3d-transition ion is orientated along a-axis in LiMnPO4, along b-axis in LiFePO4, and along c-axis in both LiNi0.9Mn0.1PO4 and LiNi0.9Co0.1PO4. At low temperatures, a magnetic moment magnitude is equal to 4.0(B) in LiMnPO4 and LiFePO4 samples, while it is twice less for LiNi0.9Co0.1PO4.
Author keywords:
Lithium-transition metal orthophosphate; crystal structure; magnetic ordering; magnetization LINIPO4; LICOPO4
DOI:
10.1080/00150193.2017.1293442
Web of Science ID:
ISI:000401196300011
Соавторы в МНС:
Другие поля
Поле Значение
Publisher TAYLOR \& FRANCIS LTD
Address 2-4 PARK SQUARE, MILTON PARK, ABINGDON OR14 4RN, OXON, ENGLAND
Language English
EISSN 1563-5112
Keywords-Plus LINIPO4; LICOPO4
Research-Areas Materials Science; Physics
Web-of-Science-Categories Materials Science, Multidisciplinary; Physics, Condensed Matter
Author-Email natali.urusova@mail.ru
Funding-Acknowledgement UrFU {[}1362]; Ministry of Education and Science of Russian Federation {[}1362]; UB RAS {[}15-8-2-2]; NRF {[}2012M2A2A6002461]; FASO of Russia {[}01201463334]
Funding-Text This research was supported by the State contract No. 1362 between UrFU and the Ministry of Education and Science of Russian Federation. This research was supported in part by Program of UB RAS No. 15-8-2-2. This work was partly supported by the Nuclear R\&D Program of Korea through the NRF grant No. 2012M2A2A6002461. Work was partially carried out in neutron center of IMP and supported by the FASO of Russia (theme ``Flux{''} No. 01201463334).
Number-of-Cited-References 9
Usage-Count-Last-180-days 4
Usage-Count-Since-2013 4
Journal-ISO Ferroelectrics
Doc-Delivery-Number EU7DV