Electrochemical and Thermodynamic Properties of Lanthanum in a Chloride Melt - Liquid Metal System / Dedyukhin A. S.,Shchetinskiy A. V.,Kharina E. A.,Shchepin I. E.,Volkovich V. A.,Yamshchikov L. F.,Osipenko A. G. // . - 2016. - V. 75, l. 15. - P. 265-274.

ISSN/EISSN:

1938-5862 / нет данных

Type:

Proceedings Paper

Abstract:

The behavior and properties of lanthanum in a ``molten salt - liquid metal{''} system in relation to pyrochemical reprocessing of spent nuclear fuels was considered. Temperature dependencies of lanthanum formal standard electrode potential, E{*}(La/La(III)), and Gibbs free energy change of lanthanum trichloride formation in LiCl-KCl-CsCl eutectic based melts were obtained between 668-976 K. The behavior of lanthanum was studied in metallic alloys based on Ga-Al (1.6 wt. \% Al) and Ga-Zn (3.64 wt. \% Zn) eutectics, and lanthanum activity, solubility and activity coefficients were determined.

Author keywords:

нет данных

DOI:

10.1149/07515.0265ecst

Web of Science ID:

ISI:000406655900026

Соавторы в МНС:

Другие поля

Поле	Значение
Editor	Haverhals, L and Mantz, R and Trulove, P and Ueda, M and Carter, M and Biddinger, EJ and Suroviec, A and Reichert, M and Endres, F and Bund, A and Ispas, A and Fox, DM and DeLong, H
Booktitle	MOLTEN SALTS AND IONIC LIQUIDS 20
Series	ECS Transactions
Note	20th Int Symposium on Molten Salts and Ionic Liquids as part of the Joint Meeting of the 230th Meeting of The Electrochemical-Society, The Electrochemical-Society-of-Japan, and the Korean-Electrochemical-Society, Honolulu, HI, OCT 02-07, 2016
Organization	Electrochem Soc; Electrochem Soc Japan; Korean Electrochem Soc; Chinese Soc Electrochemistry; Royal Australian Chem Inst, Electrochemistry Div; Japan Soc Appl Phys; Korean Phys Soc Semiconductor Div; Chinese Phys Soc, Semiconductor Phys Div; Electrochem Soc, Phys \& Analyt Electrochemistry Div; Electrochem Soc, Electrodeposit Div; Electrochem Soc, Energy Technol Div; Electrochem Soc, Sensor DIv
Publisher	ELECTROCHEMICAL SOC INC
Address	65 S MAIN ST, PENNINGTON, NJ 08534-2839 USA
Language	English
ISBN	978-1-60768-732-0
Research-Areas	Electrochemistry; Metallurgy \& Metallurgical Engineering
Web-of-Science-Categories	Electrochemistry; Metallurgy \& Metallurgical Engineering
ResearcherID-Numbers	Volkovich, Vladimir/K-8339-2012
ORCID-Numbers	Volkovich, Vladimir/0000-0003-4438-1194
Funding-Acknowledgement	Ministry of Education and Science of the Russian Federation {[}14.581.21.0002, RFMEFI58114X0002]
Funding-Text	The study was financially supported by the Ministry of Education and Science of the Russian Federation within the framework of subsidizing agreement of September 29, 2014 (No. 14.581.21.0002, unique agreement identifier RFMEFI58114X0002) of the Federal Target Program ``Research and Development in Priority Directions of the Progress of the Scientific and Technological Complex of Russia for the Years 2014-2020.{''}
Number-of-Cited-References	15
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	1
Doc-Delivery-Number	BI1PJ