Chemical Bath Deposition of Thin Nanocrystalline Tin(II) Sulfi de Films with Thioacetamide / Tulenin S. S.,Timina A. A.,Maskaeva L. N.,Markov V. F. // RUSSIAN JOURNAL OF APPLIED CHEMISTRY. - 2017. - V. 90, l. 1. - P. 91-96.

ISSN/EISSN:

1070-4272 / 1608-3296

Type:

Article

Abstract:

Nanocrystalline tin(II) sulfide layers 100-650 nm thick were prepared by hydrochemical deposition on glass-ceramic supports from a citrate system at 323-343 K using thioacetamide as chalcogenizing agent. These films are of interest for the development of thin-film solar radiation converters based on the multicomponent compound Cu2ZnSnS4 of kesterite structure, prepared using a cost-saving process. Examination by scanning electron microscopy shows that tin(II) sulfide layers are formed from spherical nanocrystallites of 20-40 nm size. X-ray diffraction analysis shows that they crystallize in the orthorhombic system with the unit cell parameters a = 4.276, b = 11.243, and c = 3.986 . Analysis by X-ray photoelectron spectroscopy revealed the presence of up to 44.86 at. \% oxygen in the surface layer of the film. This oxygen is mainly present in surface contaminants and is also incorporated in SnO present on the surface.

Author keywords:

TIN SULFIDE; COMPLEXING AGENT; GROWTH; ROUTE

DOI:

10.1134/S1070427217010141

Web of Science ID:

ISI:000400081800014

Соавторы в МНС:

Другие поля

Поле	Значение
Month	JAN
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3296
Keywords-Plus	TIN SULFIDE; COMPLEXING AGENT; GROWTH; ROUTE
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Applied
Author-Email	mln@ural.ru
Number-of-Cited-References	25
Usage-Count-Last-180-days	4
Usage-Count-Since-2013	4
Journal-ISO	Russ. J. Appl. Chem.
Doc-Delivery-Number	ET2EK