Synthesis of Symmetrical Disulfides by Reaction of Fluorine-Containing Thiiranes with Cyclic Amines / Nalet'ko S. A.,Gorbunova T. I.,Pervova M. G.,Kodess M. I.,Zapevalov A. Ya.,Saloutin V. I. // RUSSIAN JOURNAL OF ORGANIC CHEMISTRY. - 2017. - V. 53, l. 4. - P. 514-519.

ISSN/EISSN:

1070-4280 / 1608-3393

Type:

Review

Abstract:

Regioselective opening of the thiirane ring in fluorine-containing thioglycidyl ethers and {[}(perfluorobutyl)methyl]thiirane by the action of cyclic amines afforded 1,2-aminothiols which were oxidized in situ to symmetrical disulfides. The rate of formation of the latter depended on the amine basicity. According to the NMR data, the resulting disulfides were mixtures of erythro and threo diastereoisomers.

Author keywords:

SELF-ASSEMBLED MONOLAYERS; THIOLS; EFFICIENT; SULFENYLATION; OXIDATION; INDOLES; OXIDANT; ETHERS

DOI:

10.1134/S1070428017040030

Web of Science ID:

ISI:000402834000003

Соавторы в МНС:

Другие поля

Поле	Значение
Month	APR
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3393
Keywords-Plus	SELF-ASSEMBLED MONOLAYERS; THIOLS; EFFICIENT; SULFENYLATION; OXIDATION; INDOLES; OXIDANT; ETHERS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Organic
Author-Email	gorbunova@ios.uran.ru
Number-of-Cited-References	29
Journal-ISO	Russ. J. Organ. Chem.
Doc-Delivery-Number	EW9JC