The Interaction of Low- and Medium-Chlorinated Biphenyls with Sodium Methoxide with the Account for Thermodynamic Modeling / Plotnikova K. A.,Gorbunova T. I.,Pervova M. G.,Kulikova T. V.,Maiorova A. V.,Saloutin V. I.,Chupakhin O. N. // RUSSIAN JOURNAL OF GENERAL CHEMISTRY. - 2017. - V. 87, l. 5. - P. 934-939.

ISSN/EISSN:

1070-3632 / 1608-3350

Type:

Article

Abstract:

The interaction of low- and medium-chlorinated congeners of polychlorinated biphenyls of the Trikhlorbifenil technical mixture with sodium methoxide in dimethylsulfoxide has been studied by means of experimental and calculation methods. Thermodynamic modeling of the process has revealed exclusive formation of the methoxy derivatives in the studied process. whereas the experiment has revealed the formation of methoxy, hydroxy, and methoxy(hydroxy) derivatives of congeners of polychlorinated biphenyls.

Author keywords:

polychlorinated biphenyls; congener; nucleophilic substitution; thermodynamic modeling POLYCHLORINATED-BIPHENYLS; TECHNICAL MIXTURE; CONGENERS; DEGRADATION

DOI:

10.1134/S1070363217050073

Web of Science ID:

ISI:000405400000007

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	MAY
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3350
Keywords-Plus	POLYCHLORINATED-BIPHENYLS; TECHNICAL MIXTURE; CONGENERS; DEGRADATION
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	gorbunova@ios.uran.ru
Funding-Acknowledgement	Russian Foundation for Basic Research {[}16-33-00314]
Funding-Text	This work was financially supported by the Russian Foundation for Basic Research (project 16-33-00314).
Number-of-Cited-References	16
Usage-Count-Last-180-days	1
Usage-Count-Since-2013	1
Journal-ISO	Russ. J. Gen. Chem.
Doc-Delivery-Number	FA4FU