Mechanism of precipitate formation during spontaneous crystallization from supersaturated aqueous solutions / Linnikov O. D. // RUSSIAN CHEMICAL REVIEWS. - 2014. - V. 83, l. 4. - P. 343-364.

ISSN/EISSN:

0036-021X / 1468-4837

Type:

Review

Abstract:

The models of formation of salt precipitates during crystallization from supersaturated aqueous solutions are analyzed. The results of theoretical simulations and experimental studies are compared. The attention is focused on the processes of crystal aggregation and agglomeration. The data on the mechanism of crystal intergrowth under conditions of mass crystallization of salts from supersaturated aqueous solutions are considered. The intergrowth process is shown to be described most reliably by the model based on the Polak theory according to which in supersaturated solutions, connecting nucleus-bridges are formed within aggregates between the closest faces of neighbouring crystals. The bibliography includes 159 references.

Author keywords:

CALCIUM-OXALATE MONOHYDRATE; ALUMINA-TRIHYDRATE CRYSTALLIZATION; EN MILIEU CONDENSE; ETHANOL SOLUTIONS; POTASSIUM-CHLORIDE; SODIUM-CHLORIDE; PART 1; MESOCRYSTAL MICROSPHERES; AGGLOMERATION KINETICS; SECONDARY NUCLEATION

DOI:

10.1070/RC2014v083n04ABEH00439

Web of Science ID:

ISI:000335827600004

Соавторы в МНС:

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Другие поля

Поле	Значение
Publisher	TURPION LTD
Address	C/O TURPION LTD, IOP PUBLISHING, TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6HG, ENGLAND
Language	English
EISSN	1468-4837
Keywords-Plus	CALCIUM-OXALATE MONOHYDRATE; ALUMINA-TRIHYDRATE CRYSTALLIZATION; EN MILIEU CONDENSE; ETHANOL SOLUTIONS; POTASSIUM-CHLORIDE; SODIUM-CHLORIDE; PART 1; MESOCRYSTAL MICROSPHERES; AGGLOMERATION KINETICS; SECONDARY NUCLEATION
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	linnikov@mail.ru
Number-of-Cited-References	158
Usage-Count-Last-180-days	3
Usage-Count-Since-2013	26
Journal-ISO	Russ. Chem. Rev.
Doc-Delivery-Number	AH0RJ