Spontaneous crystallization of sodium chloride from aqueous-ethanol solutions; Part 3: Examination of a model of the crystallization process / Linnikov Oleg D. // CRYSTAL RESEARCH AND TECHNOLOGY. - 2007. - V. 42, l. 8. - P. 758-765.

ISSN/EISSN:

0232-1300 / нет данных

Type:

Article

Abstract:

In the present work the examination of the proposed earlier model of spontaneous crystallization process was done. The model describes kinetics of the crystallization process after the end of the induction period. To test the model the published data on crystallization and aggregation kinetics of sodium chloride at its spontaneous crystallization from supersaturated aqueous-ethanol solutions were used. It was found an excellent coincidence of the experimental and theoretical data on concentration of the salt and the total number of crystals in solution at crystallization. The model allows predicting with satisfactory accuracy kinetics of crystallization using such general parameters of sodium chloride as the specific surface energy and the height of the nucleus-bridges between crystals at coalescence.

Author keywords:

sodium chloride; supersaturated aqueous-ethanol solutions; model; spontaneous crystallization; aggregation of crystals; crystal size distribution POTASSIUM-CHLORIDE; MECHANISM; CRYSTALS; AGGREGATION; COALESCENCE; KINETICS

DOI:

10.1002/crat.200710903

Web of Science ID:

ISI:000248667400004

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	AUG
Publisher	WILEY-V C H VERLAG GMBH
Address	PO BOX 10 11 61, D-69451 WEINHEIM, GERMANY
Language	English
Keywords-Plus	POTASSIUM-CHLORIDE; MECHANISM; CRYSTALS; AGGREGATION; COALESCENCE; KINETICS
Research-Areas	Crystallography
Web-of-Science-Categories	Crystallography
Author-Email	linnikov@mail.ru
Number-of-Cited-References	13
Usage-Count-Since-2013	7
Journal-ISO	Cryst. Res. Technol.
Doc-Delivery-Number	199AA