Substituted bismuth vanadates and chromates: New aspects / Mikhaylovskaya Z. A.,Buyanova E. S.,Petrova S. A.,Morozova M. V.,Tarakina N. V.,Kuznetsov M. V. // RUSSIAN JOURNAL OF INORGANIC CHEMISTRY. - 2017. - V. 62, l. 11. - P. 1441-1449.

ISSN/EISSN:

0036-0236 / 1531-8613

Type:

Article

Abstract:

The work is devoted to the synthesis and attestation of a number of substituted vanadates and chromates of bismuth. For bismuth vanadates of the BIMEVOX family, the homogeneity regions of the Bi4V2 - x Cr (x) O-11 +/- d solid solutions have been refined, the features of the structure change of the compounds with increasing chromium content and changing temperature have been noted, and the powders and ceramics have been studied by electron microscopy. For the first time, as an impurity, an individually substituted bismuth chromate of the composition Substituted bismuth chromate of the Bi13Cr5 - y V (y) O34.5 - d (y = 0.95 +/- 0.05) composition has been detected for the first time as an impurity and synthesized as an individual compound, which has been characterized by X-ray diffraction, electron microscopy, chemical analysis, and photoelectron spectroscopy data; its homogeneity range has been determined, and electroconductive characteristics have been studied.

Author keywords:

ELECTRICAL-PROPERTIES; BI2O3-CR2O3 SYSTEM; IONIC-CONDUCTIVITY; BIMEVOX SERIES; OXIDE; ELECTROLYTES; SPECTROSCOPY; COLUMNS

DOI:

10.1134/S0036023617110122

Web of Science ID:

ISI:000415344700004

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	NOV
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1531-8613
Keywords-Plus	ELECTRICAL-PROPERTIES; BI2O3-CR2O3 SYSTEM; IONIC-CONDUCTIVITY; BIMEVOX SERIES; OXIDE; ELECTROLYTES; SPECTROSCOPY; COLUMNS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Inorganic \& Nuclear
Author-Email	zozoikina@mail.ru
Funding-Acknowledgement	Russian Foundation for Basic Research {[}16-33-60026]; Ministry of Education and Science of the Russian Federation {[}SP-3376.2016.1]
Funding-Text	This work was supported by the Russian Foundation for Basic Research (project no. 16-33-60026) and the Ministry of Education and Science of the Russian Federation (grant no. SP-3376.2016.1 from the President of the Russian Federation for Support of Young Scientists and PhD Students).
Number-of-Cited-References	29
Journal-ISO	Russ. J. Inorg. Chem.
Doc-Delivery-Number	FM8NC