A simple and efficient synthesis of 3-(polyfluoroalkyl)-propane-1,2,3-trione 2-oximes / Filyakova Vera I.,Boltachova Nadezhda S.,Pervova Marina G.,Palysaeva Nadezhda V.,Slepukhin Pavel A.,Sheremetev Aleksei B.,Charushin Valery N. // MENDELEEV COMMUNICATIONS. - 2017. - V. 27, l. 5. - P. 464-465.

ISSN/EISSN:

0959-9436 / 1364-551X

Type:

Article

Abstract:

A convenient direct synthesis of 1-aryl-3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes from the corresponding lithium 3-(polyfluoroalkyl)-1,3-diketonates has been elaborated using sodium nitrite/acetic acid system under very mild conditions. The molecular structure of 4,4-difluoro-1-phenylbutane-1,2,3-trione 2-oxime has been determined by X-ray crystallography.

Author keywords:

FLUOROALKYL

DOI:

10.1016/j.mencom.2017.09.011

Web of Science ID:

ISI:000413618800011

Соавторы в МНС:

Другие поля

Поле	Значение
Month	SEP-OCT
Publisher	ELSEVIER SCIENCE BV
Address	PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
Language	English
EISSN	1364-551X
Keywords-Plus	FLUOROALKYL
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	vif@ios.uran.ru sab@ioc.ac.ru
Funding-Acknowledgement	Federal program for support of the leading scientific schools {[}NSh 8922.2016.3]
Funding-Text	This study was supported by the Federal program for support of the leading scientific schools (grant no. NSh 8922.2016.3 for V.I.F., N.S.B., M.G.P., F.A.S. and V.N.C.).
Number-of-Cited-References	19
Journal-ISO	Mendeleev Commun.
Doc-Delivery-Number	FK6MW