Optimization of the Chemical Stage of Pretreatment of Technical Polychlorobiphenyls for Destruction / Plotnikova K. A.,Pervova M. G.,Gorbunova T. I.,Khaibulova T. Sh.,Boyarskii V. P.,Saloutin V. I.,Chupakhin O. N. // DOKLADY CHEMISTRY. - 2017. - V. 476, l. 1. - P. 206-210.

ISSN/EISSN:

0012-5008 / 1608-3113

Type:

Article

Abstract:

The reactions of commercial polychlorobiphenyl mixtures of Sovol and Trikhlorbifenil brands (Russia) with sodium methoxide were studied in dimethyl sulfoxide and methanol. It was shown for the first time that Sovol congeners are exhaustively converted, without formation of potentially toxic products, in the reaction with alkali metal alkoxide based on a monobasic aliphatic alcohol. This process is a stage of chemical pretreatment of polychlorobiphenyls subject to destruction for the subsequent microbiological mineralization of the new derivatives.

Author keywords:

POLYCHLORINATED-BIPHENYLS

DOI:

10.1134/S0012500817090038

Web of Science ID:

ISI:000412071400002

Соавторы в МНС:

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Другие поля

Поле	Значение
Month	SEP
Publisher	MAIK NAUKA/INTERPERIODICA/SPRINGER
Address	233 SPRING ST, NEW YORK, NY 10013-1578 USA
Language	English
EISSN	1608-3113
Keywords-Plus	POLYCHLORINATED-BIPHENYLS
Research-Areas	Chemistry
Web-of-Science-Categories	Chemistry, Multidisciplinary
Author-Email	pervova@ios.uran.ru
Number-of-Cited-References	12
Usage-Count-Last-180-days	3
Usage-Count-Since-2013	3
Journal-ISO	Dokl. Chem.
Doc-Delivery-Number	FI6AS