3-(4-Thiocarbamoyl-1,2,3-triazol-1-yl)benzo-15-crown-5: Synthesis and properties / Prokhorova P.E., Glukhareva T.V., Dyudya L.V., Alekseeva E.A., Morzherin Yu.Yu. // Russian Chemical Bulletin. - 2010. - V. 59, l. 4. - P. 867-869.

ISSN:

10665285

Type:

Article

Abstract:

A reaction of 1,2,3-thiadiazole-4-carbaldehyde with 3-aminobenzo-15-crown-5 involves the Cornforth rearrangement of the 1,2,3-thiadiazole ring, which leads to 1,2,3-triazole-4-carbothioamide containing the benzocrown ether substituent in position 1 of the triazole ring. Reversible formation of the isomeric thiadiazole occurs in aprotic nonpolar solvents such as deuterated chloroform. These compounds are suitable for extraction of α-amino acids from an aqueous phase. © 2010 Springer Science+Business Media, Inc.

Author keywords:

α-amino acids.; crown ether; extraction; nitrogen-containing heterocycles; rearrangement

Index keywords:

нет данных

DOI:

10.1007/s11172-010-0177-1

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-77958599063&doi=10.1007%2fs11172-010-0177-1&partnerID=40&md5=3a49bbc5c8ebd3f6c9b6e0724b0f6ccc

Соавторы в МНС:

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Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-77958599063&doi=10.1007%2fs11172-010-0177-1&partnerID=40&md5=3a49bbc5c8ebd3f6c9b6e0724b0f6ccc
Affiliations	Ural State Technical University, 19 ul. Mira, Ekaterinburg 620002, Russian Federation; A. V. Bogatsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 86 ul. Lustdorfskaya doroga, Odessa 65080, Ukraine
Author Keywords	α-amino acids.; crown ether; extraction; nitrogen-containing heterocycles; rearrangement
References	Beer, P.D., Gale, P.A., Anion recognition and sensing: The state of the art and future perspectives (2001) Angewandte Chemie - International Edition, 40 (3), pp. 486-516. , DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.0.CO;2-P; Itsikson, N.A., Geide, I.V., Morzherin, Yu., Matern, A.I., Chupakhin, O.N., (2007) Heterocycles, 72, p. 53. , 1:CAS:528:DC%2BD2sXlsFCjsrc%3D 10.3987/REV-06-SR(K)2; Kirkovits, G.J., Shriver, J.A., Gale, P.A., Sessler, J.L., Synthetic ditopic receptors (2001) Journal of Inclusion Phenomena, 41 (1-4), pp. 69-75. , DOI 10.1023/A:1014468126351; Chupakhin, O.N., Itsikson, N.A., Morzherin, Yu., Charushin, V.N., (2005) Heterocycles, 66, p. 689. , 1:CAS:528:DC%2BD28XhtV2jsLo%3D 10.3987/REV-05-SR(K)1; Glukhareva, T.V., Morzherin, Yu., Mokrushin, V.S., Tkachev, A.V., Bakulev, V.A., (2000) Khim. Geterotsikl. Soedin., p. 707. , [Chem. Heterocycl. Compd. (Engl. Transl.), 2000, 36, 626]; Glukhareva, T.V., Morzherin, Yu., Dyudya, L.V., Malysheva, K.V., Tkachev, A.V., Padva, A., Bakulev, V.A., (2004) Izy. Mad. Nauk, Ser. Khim., p. 1258. , [Russ. Chem. Bull., Int. Ed., 2004, 53, 1311]; Reichardt, C., (1988) Solvents and Solvent Effects in Organic Chemistry, , VCH Verlagsgesellschaft mbH Weinheim; Glukhareva, T.V., Dyudya, L.V., Pospelova, T.A., Bakulev, V.A., Tkachev, A.V., Morzherin, Yu., (2005) Khim. Geterotsikl. Soedin., p. 631. , [Chem. Heterocycl. Compd. (Engl. Transl.), 2005, 41, 542]
Correspondence Address	Morzherin, Yu. Yu.; Ural State Technical University, 19 ul. Mira, Ekaterinburg 620002, Russian Federation; email: morzherin@mail.ru
Language of Original Document	English
Abbreviated Source Title	Russ. Chem. Bull.
Source	Scopus