Self condensation of enamines mediated by acetylation. A novel approach to 1-(azol-5-yl)-(1E,3Z)-butadiene-4-N,N-dimethylamines / Shafran Y., Rozin Y., Beryozkina T., Zhidovinov S., Eltsov O., Subbotina J., Leban J., Novikova R., Bakulev V. // Organic and Biomolecular Chemistry. - 2012. - V. 10, l. 30. - P. 5795-5798.

ISSN:
14770520
Type:
Article
Abstract:
Novel self-condensation of 3-(azol-5-yl)-1,1-dimethylenamines has been found to form new C-C bonds leading to 2,4-(1,2,3-triazole-1,2,3-thiadiazole-3- phenylisothiazole)-(1E,3Z)-5-yl-butadiene-1-amines. The discovered reaction represents a new example of C-H functionalization in unsaturated systems and can serve an efficient synthetic approach to rational design of new 2,4-(diazole-5-yl)-dieneamines. © 2012 The Royal Society of Chemistry.
Author keywords:
Index keywords:
C-C bonds; C-H functionalization; Enamines; Rational design; Self-condensation; Synthetic approach; Acetylation; Amines; Condensation; Butadiene; biphenyl derivative; diamine; enamine; imidazole deriv
DOI:
10.1039/c2ob25331c
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-84863915113&doi=10.1039%2fc2ob25331c&partnerID=40&md5=e17357c8482f4950e9119aa4570e8294
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Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-84863915113&doi=10.1039%2fc2ob25331c&partnerID=40&md5=e17357c8482f4950e9119aa4570e8294
Affiliations TOS, Lab. of Ural Federal University Named after First President of Russia B. N. Eltsin, 19 Mira Str., 620002 Yekaterinburg, Russian Federation; I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Science, 620990 Yekaterinburg, Russian Federation; 4SC Am Klopferspitz, 19, D-82152 Planegg, Germany
Chemicals/CAS Biphenyl Compounds; Diamines; Imidazoles; enamine
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Correspondence Address Bakulev, V.; TOS, Lab. of Ural Federal University Named after First President of Russia B. N. Eltsin, 19 Mira Str., 620002 Yekaterinburg, Russian Federation; email: v.a.bakulev@ustu.ru
CODEN OBCRA
PubMed ID 22508270
Language of Original Document English
Abbreviated Source Title Org. Biomol. Chem.
Source Scopus