Reaction of 5-hydrazono-1,2,3-thiadiazoles with toluene and xylene in the presence of PCl5 / Glukhareva T.V., Dyudya L.V., Morzherin Yu.Yu., Tkachev A.V., Bakulev V.A. // Chemistry of Heterocyclic Compounds. - 2003. - V. 39, l. 1. - P. 126-127.

ISSN:

00093122

Type:

Article

Abstract:

The treatment of 5-hydrazono-1,2,3-thiadiazoles by phosphorus pentachloride in toluene or xylene leads to an anomalous Dimroth rearrangement and the reaction of the mercapto function formed with the methyl group of the solvent to give 5-benzylmercapto-1,2,3-triazole.

Author keywords:

1,2,3-thiadiazole; 1,2,3-triazole; Dimroth rearrangement

Index keywords:

5 benzylmercapto 1,2,3 triazole; 5 hydrazono 1,2,3 thiadiazole; chloride; methyl group; phosphorus pentachloride; thiadiazole derivative; toluene; triazole derivative; unclassified drug; xylene; alkyl

DOI:

10.1023/A:1023041329732

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-0037567345&doi=10.1023%2fA%3a1023041329732&partnerID=40&md5=9abd5a31970352fccbdeda28b486b4b8

Соавторы в МНС:

Другие поля

Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-0037567345&doi=10.1023%2fA%3a1023041329732&partnerID=40&md5=9abd5a31970352fccbdeda28b486b4b8
Affiliations	Urals State Technical University, Yekaterinburg 620002, Russian Federation; Novosibirsk Inst. of Organ. Chem., Novosibirsk 630090, Russian Federation
Author Keywords	1,2,3-thiadiazole; 1,2,3-triazole; Dimroth rearrangement
Chemicals/CAS	chloride, 16887-00-6; phosphorus pentachloride, 10026-13-8; toluene, 108-88-3; xylene, 1330-20-7
References	Kindt-Larsen, T., Pedersen, C., (1962) Acta Chem. Scand., 16, p. 1800; Dehaen, W., Voets, M., Bakulev, V.A., (2000) Advances in Nitrogen Heterocycles, 4, p. 37. , JAI Press, Inc., Stamford, Connecticut; Shafran, Yu.M., Bakulev, V.A., Shevyrin, V.A., Kolobov, M.Yu., (1993) Khim. Geterotsikl. Soedin., p. 840
Correspondence Address	Glukhareva, T.V.; Urals State Technical University, Yekaterinburg 620002, Russian Federation; email: morzherin@htf.ustu.ru
CODEN	CHCCA
Language of Original Document	English
Abbreviated Source Title	Chem. Heterocycl. Compd.
Source	Scopus