Carbonilation of benzen sulphonyloxyacetonitrile as a new method of synthesizing mononitrile ethyl ester of malonic acid / Lapidus A.L., Pirozhkov S.D., Tumanova A.R., Koksharova T.G., Volkova N.V., Bakulev V.A., Mokrushin V.S. // Khimiya Tverdogo Topliva. - 1993. - V. , l. 2. - P. 5-7.

ISSN:
00231177
Type:
Article
Abstract:
Mononitrile ethyl ester of malonic acid was shown to be synthesized by carbonilation of benzene sulphonyloxyacetonitrile with Co2(CO)8 as a catalyst in ethanol medium with the yield of 30% and conversion of initial product 60-90%. The effect of pressure, temperature and experiment duration on the main characteristics of the process was studied.
Author keywords:
Index keywords:
Catalysts; Esters; Ethanol; Pressure effects; Synthesis (chemical); Temperature; Benzene sulphonyloxyacetonitrile; Mononitrile ethyl ester of malonic acid; Utilization of industrial waste; Carbonylati
DOI:
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-0027554468&partnerID=40&md5=54006c60f47b013554a36c62cd35d416
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Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-0027554468&partnerID=40&md5=54006c60f47b013554a36c62cd35d416
Affiliations Inst Organicheskoj Khimii im. N.D., Zelinskogo RAN, Moscow, Russian Federation
Correspondence Address Lapidus, A.L.; Inst Organicheskoj Khimii im. N.D., Zelinskogo RAN, Moscow, Russian Federation
CODEN KTVTB
Language of Original Document Russian
Abbreviated Source Title Khim Tverd Topl
Source Scopus