Synthesis of the ethyl ester of the mononitrile of malonic acid by the catalytic carbonylation of benzenesulfonyloxyacetonitrile / Lapidus A.L., Pirozhkov S.D., Tumanova A.R., Koksharova T.G., Volkova N.V., Bakulev V.A., Mokrushin V.S. // Bulletin of the Russian Academy of Sciences Division of Chemical Science. - 1992. - V. 41, l. 1. - P. 178-180.

ISSN:

10635211

Type:

Article

Abstract:

A new method has been developed for the synthesis of the ethyl ester of the mononitrile of malonic acid by the carbonylation of benzenesulfonyloxyacetonitrile in absolute ethanol in the presence of cobalt carbonyl. The yield of the desired product was 30% with 60-90% conversion of the starting compound. The effects of temperature, pressure, and reaction time were studied. © 1992 Plenum Publishing Corporation.

Author keywords:

benzenesulfonyloxyacetonitrile; carbonylation; dicobalt octacarbonyl; ethyl ester of the mononitrile of malonic acid

Index keywords:

нет данных

DOI:

10.1007/BF00863942

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-34249832836&doi=10.1007%2fBF00863942&partnerID=40&md5=aed7857ce98bb5667fa3fff41ac73803

Соавторы в МНС:

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Другие поля

Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-34249832836&doi=10.1007%2fBF00863942&partnerID=40&md5=aed7857ce98bb5667fa3fff41ac73803
Author Keywords	benzenesulfonyloxyacetonitrile; carbonylation; dicobalt octacarbonyl; ethyl ester of the mononitrile of malonic acid
References	Kazanskii, B.A., (1949) Organic Syntheses, p. 560. , B. A., Kazanskii, Inos. Lit., Moscow, Russian translation; German Federal Republic Patent No. 2,807,625 (1982); Japanese Patent No. 59,148,751 (1984); Chem. Abstr., 102, 61807 (1982); J. Lichtenberger and C. H. Faure, Bull. Soc. Chim. Fr., 995 (1948)
Publisher	Kluwer Academic Publishers-Plenum Publishers
Language of Original Document	English
Abbreviated Source Title	Russ Chem Bull
Source	Scopus