Synthesis and properties of thiocarbamoylmethylpyridinium (isoquinolinium) ylids / Berseneva V.S., Bakulev V.A., Mokrushin V.S., Lebedev A.T. // Chemistry of Heterocyclic Compounds. - 1989. - V. 25, l. 12. - P. 1364-1368.

ISSN:
00093122
Type:
Article
Abstract:
2-(2-Carbethoxy-1-amino-1-thio)ethylenepyradinium(isoqunolinium) ylids were obtained by the reaction of carbethoxycyanomethylpyridinium(isoquinolinium) ylids with hydrogen sulfide. In an alkaline medium they cyclize into 5-mercaptosubstituted imidazo[1,2-a]pyridines(isoquinolines). The structure of the latter compounds was confirmed by PMR and IR spectroscopy. © 1990 Plenum Publishing Corporation.
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DOI:
10.1007/BF00473865
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Affiliations S. M. Kirov Ural' Polytechnical Institute, Sverdlovsk, 620002, Russian Federation
References Fisher, E., Rembaz, G., Wollin, K.M., (1978) Z. Chem., 18, p. 137; Fisher, E., Rembaz, G., Wollin, K.M., Synthese neuer Thieno [2?,3?; 4,5]imidazo[1,2-a]pyridiniumsalze (1980) J. Prakt. Chem., 322, p. 375; Sato, S., Ohta, M., The Reaction of N-Acylmethylisoquinolinium Betain with Heterocumulens (1969) Bulletin of the Chemical Society of Japan, 42, p. 2054; Krohnke, F., Steurnagel, H.H., Pyridinium-Derivate der Dithioessigsäure, II. Alkylierungen und Acylierungen (1962) Chemische Berichte, 95, p. 1118; Taylor, E.C., Turchi, I.J., (1979) Chem. Rev., 79, p. 181; Peters, D.A., McGeer, P.L., (1968) J. Physiol. Biochem., 46, p. 195; Chemistry, (1979) The Chemistry of Heterocyclic Compounds, Vol. 34, p. 612. , J. V., Metzger, Thiazole and Its Derivatives, Pt. 1, Wiley, New York; Shafran, Bakulev, V.A., Mokrushin, V.S., Validuda, G.I., (1986) Khim. Geterotsikl. Soedin., 5, p. 691; Fujito, H., Tominaga, Y., Matsuda, Y., Kobayashi, G., (1976) Heterocycles, 4, p. 939; Catten, J.P., Karafiglogluo, P., Lablache-Combier, A., Lethan, Surpatleanu, G., (1976) Tetrahedron, 32, p. 461; Krohnke, F., Über Eniminbetaine (I. Mitteil) (1939) Berichte der deutschen chemischen Gesellschaft (A and B Series), 72, p. 83
Correspondence Address Berseneva, V.S.; S. M. Kirov Ural' Polytechnical Institute, Sverdlovsk, 620002, Russian Federation
Publisher Kluwer Academic Publishers-Plenum Publishers
CODEN CHCCA
Language of Original Document English
Abbreviated Source Title Chem Heterocycl Compd
Source Scopus