Dual reactivity of 2-diazo-2-cyanoacetamide relative to hydrogen sulfide / Bakulev V.A., Kolobov M.Yu., Grishakov A.N., Mokrushin V.S. // Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. - 1988. - V. 37, l. 1. - P. 178-180.

ISSN:

05685230

Type:

Article

Abstract:

1. Intramolecular catalysis of the amide group was found in the addition of H2S to the cyano group of 2-diazo-2-cyanoacetamides to give high yields of amides of 5-amino-1,2,3-thiadiazole-4-carboxylic acid. 2. The reactions of 2-diazo-2-cyanoacetamides with H2S in the presence of bases give the reduction of the diazo group by hydrogen sulfide in addition to heterocyclization. © 1988 Plenum Publishing Corporation.

Author keywords:

Index keywords:

нет данных

DOI:

10.1007/BF00962685

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https://www.scopus.com/inward/record.uri?eid=2-s2.0-34249973995&doi=10.1007%2fBF00962685&partnerID=40&md5=7f0037da6039ccd820e4c46655fb80e3

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Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-34249973995&doi=10.1007%2fBF00962685&partnerID=40&md5=7f0037da6039ccd820e4c46655fb80e3
Affiliations	Institute of Chemistry, Urals Branch, Academy of Sciences of the USSR, Sverdlovsk, Russian Federation
References	Shafran, Bakulev, V.A., Mokrushin, V.S., Validuda, G.I., (1986) Khim. Geterotsikl. Soedin., 5, p. 691; US Patent No. 3,787,434; Ref. Zh. Khim., No. 10, 406 (1975); Zil'berman, E.N., (1972) The Reactions of Nitriles lin Russian], p. 183. , Izd. Khimiya, Moscow
Correspondence Address	Bakulev, V.A.; Institute of Chemistry, Urals Branch, Academy of Sciences of the USSR, Sverdlovsk, Russian Federation
Publisher	Kluwer Academic Publishers-Plenum Publishers
Language of Original Document	English
Abbreviated Source Title	Russ Chem Bull
Source	Scopus