Self-condensation of 3-cyanothiochromone upon the action of benzyl- and phenethylamine / Sosnovskikh V.Y., Sevenard D.V., Moshkin V.S., El'Tsov O.S. // Russian Chemical Bulletin. - 2010. - V. 59, l. 11. - P. 2155-2158.

ISSN:
10665285
Type:
Article
Abstract:
Reflux of 3-cyanothiochromone with benzylamine in toluene afforded 17-benzyl-6,7,14,15-tetrahydro-7,15-epiminobis(8H,16H-dithiochromeno)[2,3-b: 2′,3′-f][1,5]diazocine-6,14-dione, the self-condensation product of 2-amino-3-(benzyliminomethyl)thiochromone. Similar reaction with phenethylamine leads to 2-(thiochromon-3-yl)-5H-thiochromeno[2,3-d]-pyrimidin-5-one. Mechanism of formation of the dimeric products was considered. © 2010 Springer Science+Business Media, Inc.
Author keywords:
17-benzyl-6,7,14,15-tetrahydro-7,15-epiminobis(8H,16H-dithiochromeno)[2,3-b: 2′,3′-f]-[1,5]diazocine-6,14-dione; 2-(4-oxo-4H-thiochromen-3-yl)-5H- thiochromeno[2,3-d]pyrimidin-5-one; 3-cyanothiochromone; benzylamine; phenethylamines; self-condensation
Index keywords:
нет данных
DOI:
10.1007/s11172-010-0373-z
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Affiliations A. M. Gorky Ural State University, 51 prosp. Lenina, Ekaterinburg 620083, Russian Federation; Hansa Fine Chemicals GmbH, BITZ, 1 Fahrenheitstrasse, Bremen 28359, Germany; B. N. Eltsyn Ural Federal Technical University, 19 ul. Mira, Ekaterinburg 620002, Russian Federation
Author Keywords 17-benzyl-6,7,14,15-tetrahydro-7,15-epiminobis(8H,16H-dithiochromeno)[2,3-b: 2′,3′-f]-[1,5]diazocine-6,14-dione; 2-(4-oxo-4H-thiochromen-3-yl)-5H- thiochromeno[2,3-d]pyrimidin-5-one; 3-cyanothiochromone; benzylamine; phenethylamines; self-condensation
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Correspondence Address Sosnovskikh, V. Y.; A. M. Gorky Ural State University, 51 prosp. Lenina, Ekaterinburg 620083, Russian Federation; email: vyacheslav.sosnovskikh@usu.ru
Language of Original Document English
Abbreviated Source Title Russ. Chem. Bull.
Source Scopus