Miscibility studies in poly(methyl vinyl ether)/hydroxypropylcellulose binary system in aqueous solutions and solid state / Nurkeeva Z.S., Tyukova I.S., Suvorova A.I., Mun G.A., Dzhusupbekova A.B., Khutoryanskiy V.V. // Carbohydrate Polymers. - 2005. - V. 62, l. 1. - P. 80-86.

ISSN:
01448617
Type:
Article
Abstract:
The phase separation behaviour in aqueous mixtures of poly(methyl vinyl ether) and hydroxypropylcellulose has been studied by cloud points method and viscometric measurements. The miscibility of these blends in solid state has been assessed by infrared spectroscopy; methanol vapours sorption experiments and scanning electron microscopy. The values of Gibbs energy of mixing of the polymers and their blends with methanol as well as between each other were calculated. It was found that in solid state the polymers can interact with methanol very well but the polymer-polymer interactions are unfavourable. Although in aqueous solutions the polymers exhibit some intermolecular interactions their solid blends are not completely miscible. © 2005 Elsevier Ltd. All rights reserved.
Author keywords:
Lower critical solution temperature; Miscibility; Polymeric films; Thermodynamics
Index keywords:
Ethers; Gibbs free energy; Plastic films; Scanning electron microscopy; Solubility; Thermodynamics; Viscosity measurement; Intermolecular interactions; Lower critical solution temperature; Polymeric f
DOI:
10.1016/j.carbpol.2005.06.023
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Affiliations Department of Chemical Physics and Macromolecular Chemistry, Faculty of Chemistry, Kazakh National University, 95 Karasai Batyra Street, 480012 Almaty, Kazakhstan; Faculty of Chemistry, Ural State University, 51 Lenin Ave., 620083 Ekaterinburg, Russian Federation; School of Pharmacy, University of Reading, Whiteknights, RG6 6AJ, Reading, Berkshire, United Kingdom
Author Keywords Lower critical solution temperature; Miscibility; Polymeric films; Thermodynamics
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Correspondence Address Khutoryanskiy, V.V.; Department of Chemical Physics and Macromolecular Chemistry, Faculty of Chemistry, Kazakh National University, 95 Karasai Batyra Street, 480012 Almaty, Kazakhstan; email: v.khutoryanskiy@reading.ac.uk
CODEN CAPOD
Language of Original Document English
Abbreviated Source Title Carbohydr Polym
Source Scopus