The crystal structure and oxygen nonstoichiometry of layered perovskites GdBaCo 2 - xFe xO 6 - δ (x =0; 0.2; 0.4; 0.6) / Ivanov I.L., Tsvetkov D.S. // Physics of Particles and Nuclei Letters. - 2011. - V. 8, l. 10. - P. 1056-1057.

ISSN:
15474771
Type:
Article
Abstract:
We study the effect of sublattice doping of cobalt on a crystal structure and oxygen nonstoichiometry of cobaltites GdBaCo 2 - xFe xO 6 - δ (x = 0 - 0. 6), which have considerable oxygen nonstoichiometry and show high values of oxygen-ionic and electronic conduction. These properties can be varied easily by a doping of oxide. We obtained the temperature dependences of the parameters of an elementary lattice in the range 25-800°C. © 2011 Pleiades Publishing, Ltd.
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DOI:
10.1134/S1547477111100074
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Affiliations Gorky Ural State University, Lenininskii pr. 51, Yekaterinburg 620000, Russian Federation
References Maignan, A., Martin, C., Pelloquin, D., Nguyen, N., Raveau, B., Structural and Magnetic Studies of Ordered Oxygen-Deficient Perovskites LnBaCo 2O 5 + d, Closely Related to the '112' Structure (1999) J. Solid State Chem., 142, pp. 247-260; Taskin, A.A., Lavrov, A.N., Ando, Y., Transport and Magnetic Properties of GdBaCo 2O 5 + d Single Crystals: A Cobalt Oxide with Square-Lattice CoO 2 Planes over A Wide Range of Electron and Hole Doping (2005) Phys. Rev. B, 71, pp. 134414-1-134414-28; Taranco'N, A., Marrero-Lo'pez, D., Pefia-Martinez, J., Ruiz-Morales, J.C., Nu'ñez, P., Effect of Phase Transition on High-Temperature Electrical Properties of GdBaCo 2O 5 + x Layered Perovskite (2008) Solid State Ionics, 179, pp. 611-618; Hunter, B.A., RIETICA, Version 1.7.7 (1997) IUCR Powder Diffract., 22, pp. 21-26; Mizusaki, J., Mima, Y., Yamauchi, S., Fueki, K., Tagawa, H., Nonstoichiometry of the Perovskite-Type Oxides La 1 - xSr xCoO 3 - δ (1989) J. Solid State Chem., 80, pp. 102-111
Correspondence Address Ivanov, I. L.; Gorky Ural State University, Lenininskii pr. 51, Yekaterinburg 620000, Russian Federation; email: ivanov.ivan@e1.ru
Language of Original Document English
Abbreviated Source Title Phys. Part. Nucl. Lett.
Source Scopus