Cyclic peroxides and related initiating systems for radical polymerization of methyl methacrylate / Islamova R.M., Ishkinina O.I., Nazarova S.V., Chupakhin O.N., Utepova I.A., Andriyashina N.M., Terent'Ev A.O. // Russian Chemical Bulletin. - 2013. - V. 62, l. 5. - P. 1282-1285.

ISSN:

10665285

Type:

Article

Abstract:

Cyclic peroxides as initiators for the radical polymerization of methyl methacrylate were proposed. The initial rates, initiation rates, and effective activation energies of polymerization initiated by cyclic peroxides and cyclic peroxide-1-pyridyl-2-ferrocene systems were determined. The radical yields to the volume upon the thermal decomposition of cyclic peroxides and their catalytic decomposition in the presence of 1-pyridyl-2-ferrocene were determined. In combination with 1-pyridyl-2-ferrocene cyclic peroxides form efficient initiating systems favoring an increase in the polymerization rate, a decrease in the molecular weights, and an increase in syndiotacticity of the synthesized poly(methyl methacrylate). © 2013 Springer Science+Business Media New York.

Author keywords:

1-pyridyl-2-ferrocene; cyclic peroxides; initiating systems; initiators; kinetic parameters; molecular characteristics; radical polymerization

Index keywords:

нет данных

DOI:

10.1007/s11172-013-0177-z

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https://www.scopus.com/inward/record.uri?eid=2-s2.0-84894658403&doi=10.1007%2fs11172-013-0177-z&partnerID=40&md5=5a5e594478c8784689cb66e7becc0d72

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Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-84894658403&doi=10.1007%2fs11172-013-0177-z&partnerID=40&md5=5a5e594478c8784689cb66e7becc0d72
Affiliations	Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation; Bashkir State Agrarian University, 34 ul. 50 let Oktyabrya, 450001 Ufa, Russian Federation; Ural Federal University Named after the First President of Russia B. N. Yeltsin, 19 ul. Mira, 620002 Yekaterinburg, Russian Federation; N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation
Author Keywords	1-pyridyl-2-ferrocene; cyclic peroxides; initiating systems; initiators; kinetic parameters; molecular characteristics; radical polymerization
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Correspondence Address	Islamova, R.M.; Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation; email: rmislamova@mail.ru
CODEN	RCBUE
Language of Original Document	English
Abbreviated Source Title	Russ. Chem. Bull.
Source	Scopus