The activity of element dioxides in liquid-phase oxidation of 2,3,5-trimethyl-1,4-hydroquinone / Shishmakov A.B., Kharchuk V.G., Kuznetsova O.V., Mikushina Yu.V., Koryakova O.V., Kovaleva E.G., Petrov L.A., Molochnikov L.S., Chupakhin O.N. // Russian Journal of Physical Chemistry A. - 2003. - V. 77, l. 4. - P. 548-552.

ISSN:

00360244

Type:

Article

Abstract:

The influence of silicon, tin, and titanium dioxide hydrogels on liquid-phase oxidative dehydrogenation of 2,3,5-trimethyl-1,4-hydroquinone in an aqueous-methanolic solution was studied by the method of initial reaction rates. The introduction of the gels inhibited the reaction, whereas Cu2+-containing gels accelerated it. The formation of Cu2+ compounds of various types in the gel phases was studied by EPR spectroscopy. The reactivities of these compounds were estimated.

Author keywords:

Index keywords:

2,3,5 trimethyl 1,4 hydroquinone; copper ion; hydroquinone derivative; methanol; oxide; silicon; tin; titanium dioxide; unclassified drug; aqueous solution; article; chemical analysis; chemical parame

DOI:

нет данных

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Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-0038301215&partnerID=40&md5=2fa2757c78cd3dadf78b2c28b03e5078
Affiliations	Institute of Organic Synthesis, Ural Division, Russian Academy of Sciences, Yekaterinburg, Russian Federation; Ural State Forestry Academy, Yekaterinburg, Russian Federation
Chemicals/CAS	methanol, 67-56-1; oxide, 16833-27-5; silicon, 7440-21-3; tin, 14314-35-3, 7440-31-5; titanium dioxide, 1317-70-0, 1317-80-2, 13463-67-7, 51745-87-0
References	Nakao, J., Kaeriyma, K., (1989) J. Colloid Interface Sci., 131 (1), p. 186; Isiya, O., (1989) Chem. Ind., 42 (10), p. 1822; Mc Murray, H.N., (1994) J. Phys. Chem., 98 (39), p. 9861; Lu, H., Wang, H., Liu, H., (1993) Acta Polum. Sin., (39), p. 100; Tau Van Min', Nguen Van Tusi, Rudenko, A.P., (1995) Vestn. Mosk. Univ., Ser. 2: Khim., 36 (2), p. 278; Iler, R.K., (1979) The Chemistry of Silica, Solubility, Polymerization, Colloid and Surface Properties, and Biochemistry of Silica, , New York: Wiley. Translated under the title Kolloidnaya khimiya kremnezema i silikatov, Moscow: Mir, 1986; Kharchuk, V.G., Kolenko, I.P., Petrov, L.A., Gus'kova, L.M., (1986) Zh. Org. Khim., 22 (11), p. 2306; Bellamy, L.J., (1960) The Infra-Red Spectra of Complex Molecules, , London: Methuen. Translated under the title Infrakrasnye spektry slozhnykh molekul, Moscow: Inostrannaya Literatura, 1963; Petrov, L.A., Kharchuk, V.G., Shishmakov, A.B., Tokarev, E.A., (1998) Zh. Org. Khim., 34 (3), p. 376; Poznak, S.K., Pergushov, V.I., Kokorin, A.I., Kulak, A.I., Schlapfer, C.W., (1999) J. Phys. Chem. B, 103, p. 1308; Kurmanguzhina, L.K., Marov, I.N., Evtikova, G.A., Fakeev, A.A., (1991) Vysokochist. Veshchestva, (4), p. 144; Vishnevskaya, G.P., Safin, R.Sh., Lipunov, I.N., (1975) Teor. Eksp. Khim., 11 (5), p. 651; Vishnevskaja, G.P., Saphin, R.Sh., Molotchnikov, L.S., (1977) Mol. Phys., 34 (5), p. 1329; Vishnevskaya, G.P., Safin, R.Sh., Kozyrev, B.M., (1974) Dokl. Akad. Nauk SSSR, 219 (2), p. 371; Frolova, E.N., The structural organization of mono- and polymetallic forms of ion exchangers according to EPR data (1994) Cand. Sci. (Phys.-Math.) Dissertation, , Kazan; Nikitaev, A.T., Pomogailo, A.D., Golubeva, N.D., Ivleva, I.N., (1986) Kinet. Katal., 27 (3), p. 709; Shaikhutdinov, Sh.K., Trukhan, E.M., Astanina, A.N., Molochnikov, L.S., (1986) Zh. Fiz. Khim., 60 (4), p. 997; Min' Tyau Van, Tuen Nguen Van, Rudenko, A.P., (1995) Vestn. Mosk. Univ., Ser. 2: Khim., 36 (3), p. 278
Correspondence Address	Shishmakov, A.B.; Institute of Organic Synthesis, Ural Division, Russian Academy of Sciences, Yekaterinburg, Russian Federation
Language of Original Document	English
Abbreviated Source Title	Russ. J. Phys. Chem. A
Source	Scopus