Local manifestations of a static magnetoelectric effect in nanostructured BaTiO3-BaFe12O9 composite multiferroics / Trivedi H., Shvartsman V.V., Lupascu D.C., Medeiros M.S.A., Pullar R.C., Kholkin A.L., Zelenovskiy P., Sosnovskikh A., Shur V.Y. // Nanoscale. - 2015. - V. 7, l. 10. - P. 4489-4496.

ISSN:
20403364
Type:
Article
Abstract:
A study on magnetoelectric phenomena in the barium titanate-barium hexaferrite (BaTiO3-BaFe12O19) composite system, using high resolution techniques including switching spectroscopy piezoresponse force microscopy (SSPFM) and spatially resolved confocal Raman microscopy (CRM), is presented. It is found that both the local piezoelectric coefficient and polarization switching parameters change on the application of an external magnetic field. The latter effect is rationalized by the influence of magnetostrictive stress on the domain dynamics. Processing of the Raman spectral data using principal component analysis (PCA) and self-modelling curve resolution (SMCR) allowed us to achieve high resolution phase distribution maps along with separation of average and localized spectral components. A significant effect of the magnetic field on the Raman spectra of the BaTiO3 phase has been revealed. The observed changes are comparable with the classical pressure dependent studies on BaTiO3, confirming the strain mediated character of the magnetoelectric coupling in the studied composites. This journal is © The Royal Society of Chemistry.
Author keywords:
Index keywords:
Barium; Barium compounds; Magnetic fields; Piezoelectricity; Scanning probe microscopy; Confocal Raman microscopy; External magnetic field; High-resolution techniques; Magnetoelectric couplings; Piezo
DOI:
10.1039/c4nr05657d
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-84923972743&doi=10.1039%2fc4nr05657d&partnerID=40&md5=d2fe93668c6b7b328edce2a1b162c467
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Affiliations Institute for Materials Science, Centre for Nanointegration Duisburg-Essen (CeNIDE), University of Duisburg-Essen, Essen, Germany; Department of Materials and Ceramic Engineering, CICECO, University of Aveiro, Aveiro, Portugal; Department of Materials, Imperial College London, South Kensington Campus, London, United Kingdom; Institute of Natural Sciences, Ural Federal University, Ekaterinburg, Russian Federation
Funding Details Ministry of Education and Science
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Correspondence Address Trivedi, H.; Institute for Materials Science, Centre for Nanointegration Duisburg-Essen (CeNIDE), University of Duisburg-EssenGermany
Publisher Royal Society of Chemistry
Language of Original Document English
Abbreviated Source Title Nanoscale
Source Scopus