Growth and concentration dependencies of rare-earth doped lithium niobate single crystals / Palatnikov M.N., Biryukova I.V., Sidorov N.V., Denisov A.V., Kalinnikov V.T., Smith P.G.R., Shur V.Ya. // Journal of Crystal Growth. - 2006. - V. 291, l. 2. - P. 390-397.

ISSN:
00220248
Type:
Article
Abstract:
A series of lithium niobate LiNbO3 (LN) single crystals doped by rare-earth elements (Tm, Er, Dy, Tb, Gd, Pr) were grown under the same conditions by the Czochralski technique in a wide range of dopant concentrations. The distribution coefficients of rare-earth elements in the "crystal-melt" system of LN were determined at the beginning of the crystal growth. Their dependence on the dopant concentration in melt ranging from 0.1 to 3.5 wt% was investigated. Concentration dependences of physicochemical, ferroelectric and structural characteristics of doped LN single crystals were studied using X-ray diffraction, thermal analysis and Raman scattering measurements. A mechanism of rare-earth elements incorporation into the crystal lattice of LN was proposed for a wide range of dopant concentrations. © 2006 Elsevier B.V. All rights reserved.
Author keywords:
A1. Crystal structure; A1. Doping; A1. Point defects; A2. Single crystals growth; B1. Niobates; B2. Ferroelectric materials
Index keywords:
Concentration (process); Crystal growth; Crystal structure; Doping (additives); Ferroelectric materials; Ferroelectricity; Lithium compounds; Point defects; Raman scattering; Czochralski technique; Ni
DOI:
10.1016/j.jcrysgro.2006.03.022
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Affiliations Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Science Centre, Russian Academy of Science, Apatity, Russian Federation; Russian Center of Laser Physics, Research Institute, St. Petersburg State University, St. Petersburg, Russian Federation; Optical Research Center, Southampton University, Southampton, United Kingdom; Ferroelectric Laboratory, Ural State University, Ekaterinburg, Russian Federation
Author Keywords A1. Crystal structure; A1. Doping; A1. Point defects; A2. Single crystals growth; B1. Niobates; B2. Ferroelectric materials
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Correspondence Address Palatnikov, M.N.; Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Science Centre, Russian Academy of Science, Apatity, Russian Federation; email: palat_mn@chemy.kolasc.net.ru
CODEN JCRGA
Language of Original Document English
Abbreviated Source Title J Cryst Growth
Source Scopus