An analysis of quadrupole splitting of the Mössbauer spectra of ferritin and iron-dextran complexes in relation to the iron core microstructural variations / Oshtrakh M.I., Milder O.B., Semionkin V.A., Prokopenko P.G., Livshits A.B., Kozlov A.A., Pikulev A.I. // Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences. - 2002. - V. 57, l. 6-7. - P. 566-574.

ISSN:

09320784

Type:

Conference Paper

Abstract:

Mössbauer spectra of human liver ferritin and some pharmaceutically important iron-dextran complexes as ferritin models were measured at 87 K (frozen solutions) and at both 87 and 295 K (lyophilized forms). The Mössbauer spectra consisted of paramagnetic doublets only. However, the spectral line shapes were not Lorentzian and these Mössbauer spectra were better fitted using a superposition of two or more quadrupole doublets or using a distribution of quadrupole splittings. The differences of the maximal quantity of quadrupole doublets for better fitting of various Mössbauer spectra of ferritin and iron-dextran complexes were compared with the fitting using the distribution of quadrupole splitting for additional analysis. It is possible that variations of the quantity of quadrupole doublets for better fitting of Mössbauer spectra of ferritin and iron-dextran complexes may be related to heterogeneous iron cores in the samples. This heterogeneity is supposed to be different for various samples and changed for lyophilized samples and for frozen solutions as well as for various temperatures.

Author keywords:

Ferritin; Iron-Dextran Complexes; Mössbauer Spectroscopy; Paramagnetic Iron Core; Quadrupole Splitting

Index keywords:

нет данных

DOI:

нет данных

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Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-0036616093&partnerID=40&md5=d2f3beaf88f5cbb1e9ecd29944964b7f
Affiliations	Division of Applied Biophysics, Faculty of PTDQC, Ural State Technical University, Ekaterinburg 620002, Russian Federation
Author Keywords	Ferritin; Iron-Dextran Complexes; Mössbauer Spectroscopy; Paramagnetic Iron Core; Quadrupole Splitting
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Correspondence Address	Oshtrakh, M.I.; Division of Applied Biophysics, Faculty of PTDQC, Ural State Technical University, Ekaterinburg 620002, Russian Federation; email: oshtrakh@mail.utnet.ru
Language of Original Document	English
Abbreviated Source Title	Z. Naturforsch. Sect. A J. Phys. Sci.
Source	Scopus