Synthesis and kinetics of the cyclization of 3-(dialkylaminophenyl)-2- (phenylcarbonyl)-prop-2-enenitriles / Platonova A.Y., Glukhareva T.V., Zimovets O.A., El'Tsov O.S., Morzherin Y.Y. // Chemistry of Heterocyclic Compounds. - 2013. - V. 49, l. 5. - P. 736-745.

ISSN:
00093122
Type:
Article
Abstract:
The reaction of ortho-(N,N-dialkylamino)benzaldehydes with benzoylacetonitrile gave fused 1,2,3,4-tetra-hydroquinolino-5-carbonitriles due to cyclization of the intermediate 2-(phenylcarbonyl)-3-[2-[(dialkyl-amino) phenyl]prop-2-enenitriles through a tert-amino effect mechanism. Kinetic studies were carried out on the cyclization of 2-(phenylcarbonyl)-3-[2-(piperidin-1-yl) phenyl]prop-2-enenitrile. © 2013 Springer Science+Business Media New York.
Author keywords:
1,2,3,4-tetrahydroquinolines; cyclization; N,N-dialkyl-o-vinylanilines; reaction kinetics; stereoselectivity; tert-amino effect
Index keywords:
нет данных
DOI:
10.1007/s10593-013-1305-2
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Link https://www.scopus.com/inward/record.uri?eid=2-s2.0-84882858124&doi=10.1007%2fs10593-013-1305-2&partnerID=40&md5=9b7d5f7f9706a5234b35aa2e683da1b4
Affiliations Ural Federal University, 28 Mira St., 620002 Yekaterinburg, Russian Federation
Author Keywords 1,2,3,4-tetrahydroquinolines; cyclization; N,N-dialkyl-o-vinylanilines; reaction kinetics; stereoselectivity; tert-amino effect
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Correspondence Address Platonova, A.Y.; Ural Federal University, 28 Mira St., 620002 Yekaterinburg, Russian Federation; email: alena-platonova@mail.ru
CODEN CHCCA
Language of Original Document English
Abbreviated Source Title Chem. Heterocycl. Compd.
Source Scopus