Investigation of s,p,d-element niobates and their solid solution formation processes by thermal analysis / Zhukovsky V.M., Podkorytov A.L. // Journal of Thermal Analysis and Calorimetry. - 2000. - V. 60, l. 2. - P. 523-534.

ISSN:

13886150

Type:

Article

Abstract:

The binary and ternary systems M'O(M'CO 3)-Nb 2O 5 and M'O(M'CO 3)-MO-Nb 2O 5, where M'=Ca, Sr and Ba and M=Cu, Ni, Cd, Zn and Pb, were investigated by means of thermal analysis in the temperature range 20-1500°C. The boundaries of stability of the solid solutions Sr 2-xMe xNb 2O 7, Sr 2-xM xNb 2O 7, Sr 4-xM xNb 2O 9 and Sr 6-xM xNb 2O 11 were determined by means of X-ray diffraction, and IR and Raman spectroscopy. The possibility of prognostication of the phase fields of stable solid solutions by calculation from the diagrams of the 'comparative electronegativity of atom vs. tolerance factor' was demonstrated. The kinetic parameters of the interactions in the SrCO 3+MO+Nb 2O 5 powder mixtures were established.

Author keywords:

Index keywords:

Atoms; Binary mixtures; Infrared spectroscopy; Niobium compounds; Powder metals; Raman spectroscopy; Reaction kinetics; Solid solutions; Ternary systems; Thermodynamic stability; X ray diffraction ana

DOI:

10.1023/A:1010138803352

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-0033721898&doi=10.1023%2fA%3a1010138803352&partnerID=40&md5=30f6cf3ecaa3e9c6728649ab3c712450

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Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-0033721898&doi=10.1023%2fA%3a1010138803352&partnerID=40&md5=30f6cf3ecaa3e9c6728649ab3c712450
Affiliations	Department of Chemistry, Ural State University, pr. Lenina 51, 620083, Ekaterinburg, Russian Federation
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Correspondence Address	Zhukovsky, V.M.; Ural State Univ, Ekaterinburg, Russian Federation
Publisher	Kluwer Academic Publishers, Dordrecht, Netherlands
Language of Original Document	English
Abbreviated Source Title	J Therm Anal Calor
Source	Scopus