Electrodeposition of copper on metal-filled composite support / Rudoi V.M., Ostanina T.N., Darintseva A.B., Ostanin N.I., Alikhanova I.A., Demakov S.L., Prokof'eva A.S. // Russian Journal of Electrochemistry. - 2010. - V. 46, l. 6. - P. 702-706.

ISSN:

10231935

Type:

Article

Abstract:

When a metal is deposited onto low-conductive supports, the metal deposit propagates from the contact site over the electrode surface. In the work, a mathematic model of variation in the overvoltage in the course of galvanostatic growth of copper deposit is proposed. The model takes into account the kinetic parameters of electrodeposition and geometric characteristics of growing deposit, which were obtained by using independent measurements. The chronopotentiograms, which were calculated by the model, agree satisfactorily with the experimental data. This allows one to apply the model proposed for estimating the tangential growth rate by the kinetic parameters of electrodeposition and structural characteristics of deposit. © Pleiades Publishing, Ltd., 2010.

Author keywords:

Copper deposit; Electrocrystallization; Galvanostatic conditions; Kinetic parameters; Mathematic model; Metal-filled composite

Index keywords:

Chronopotentiograms; Contact sites; Electrocrystallization; Electrode surfaces; Experimental data; Filled composites; Galvanostatic conditions; Galvanostatics; Geometric characteristics; Independent m

DOI:

10.1134/S1023193510060157

Смотреть в Scopus:

https://www.scopus.com/inward/record.uri?eid=2-s2.0-77955902342&doi=10.1134%2fS1023193510060157&partnerID=40&md5=86eb3d62db2bc9a28b65704588c64430

Соавторы в МНС:

Другие поля

Поле	Значение
Link	https://www.scopus.com/inward/record.uri?eid=2-s2.0-77955902342&doi=10.1134%2fS1023193510060157&partnerID=40&md5=86eb3d62db2bc9a28b65704588c64430
Affiliations	Yeltsin Ural State Technical University, ul. Mira 19, Yekaterinburg, 620002, Russian Federation
Author Keywords	Copper deposit; Electrocrystallization; Galvanostatic conditions; Kinetic parameters; Mathematic model; Metal-filled composite
References	Shalkauskas, M., Vashkyalis, A., (1985) Chemical Metallization of Plastics, , Khimicheskaya metallizatsiya plastmass, Leningrad: Khimiya; Saadakov, G.A., (2004) Galvanoplastics, , Gal'vanoplastika, Moscow: Mashinostroenie; Sarto, F., Larciprete, M.C., Sarto, M.S., Sibilia, C., (2003) Rev. Adv. Mater. Sci., 5, p. 34; Rudoi, V.M., Ostanina, T.N., Darintseva, A.B., Ostanin, N.I., Shtyrba, N.I., Alikhanova, I.A., Demakov, S.L., Prokof'eva, A.S., (2009) Gal'vanotekh. Obrab. Poverkhn., 17 (2), p. 17; Gamburg, Yu.D., (2006) Electroplated Coatings, , Gal'vanicheskie pokrytiya, Moscow: Tekhnosfera; Damaskin, B.B., Petrii, O.A., Tsirlina, G.A., (2001) Electrochemistry, , Elektrokhimiya, Moscow: Khimiya
Correspondence Address	Rudoi, V. M.; Yeltsin Ural State Technical University, ul. Mira 19, Yekaterinburg, 620002, Russian Federation; email: VLMX@rambler.ru
CODEN	RJELE
Language of Original Document	English
Abbreviated Source Title	Russ J Electrochem
Source	Scopus