Phase equilibria and crystal structure of the solid solution LaFe1-xNixO3-δ (0 ≤ x ≤ 1) / Proskurnina N.V., Voronin V.I., Cherepanov V.A., Kiselev E.A. // Progress in Solid State Chemistry. - 2007. - V. 35, l. 2-4 SPEC. ISS.. - P. 233-239.

ISSN:
00796786
Type:
Review
Abstract:
Phase equilibria in the LaFeO3-"LaNiO3" were studied at 1100 °C in air. The samples were synthesized by standard ceramic and/or solution route via nitrate or citrate precursors. According to the results of XRD it was found that the homogeneity ranges of LaFe1-xNixO3-δ solid solution lay within 0.0 ≤ x ≤ 0.4 (sp.gr. Pbnm) and 0.6 ≤ x ≤ 0.8 (sp.gr. R over(3, -) c). The structural parameters (bond lengths, atom coordinates) for the single-phase samples were refined using Rietveld analysis. The unit cell parameters versus LaFe1-xNixO3-δ composition are presented. © 2007 Elsevier Ltd. All rights reserved.
Author keywords:
Index keywords:
Crystal structure; Phase equilibria; Reaction kinetics; Solid solutions; Synthesis (chemical); Homogeneity; Structural parameters; Lanthanum compounds
DOI:
10.1016/j.progsolidstchem.2007
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Affiliations Institute for Metal Physics, Ural Branch, RAS, Ekaterinburg, Russian Federation; Ural State University, Department of Chemistry, Ekaterinburg, Russian Federation
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Correspondence Address Proskurnina, N.V.; Institute for Metal Physics, Ural Branch, RAS, Ekaterinburg, Russian Federation; email: proskurnina@imp.uran.ru
CODEN PSSTA
Language of Original Document English
Abbreviated Source Title Prog Solid State Chem
Source Scopus