Hydrogen reduction of vanadium in vanadium-doped LiMnPO4 / Kellerman D.G., Chukalkin Y.G., Medvedeva N.I., Kuznetsov M.V., Mukhina N.A., Semenova A.S., Gorshkov V.S. // Materials Chemistry and Physics. - 2015. - V. 149, l. . - P. 209-215.

ISSN:
02540584
Type:
Article
Abstract:
The samples of vanadium-doped LiMnPO4 have been sthesized by the solid-state reaction technique. To reduce the oxidation state of vanadium from V5+ to V4+, the samples have been additionally annealed under hydrogen atmosphere. The tetravalent state of vanadium was proved by analysis of V 2p X-ray photoelectron spectra. Raman spectroscopy, first-principle studies and magnetic measurements were used to determine the effect of V4+ on the Li-Mn phosphate properties. © 2014 Elsevier B.V. All rights reserved.
Author keywords:
Inorganic compounds; Magnetic properties ab initio calculations; Neutron scattering and diffraction; Photoelectron spectroscopy; Raman spectroscopy and scattering
Index keywords:
Calculations; Hydrogen; Inorganic compounds; Manganese; Neutron scattering; Photoelectron spectroscopy; Photoelectrons; Photons; Raman spectroscopy; Solid state reactions; Ab initio calculations; Firs
DOI:
10.1016/j.matchemphys.2014.10.
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Affiliations Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya st., 91, Ekaterinburg, Russian Federation; Ural Federal University, Ekaterinburg, Russian Federation; Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, Ekaterinburg, Russian Federation; Eliont LLC, Ekaterinburg, Russian Federation
Author Keywords Inorganic compounds; Magnetic properties ab initio calculations; Neutron scattering and diffraction; Photoelectron spectroscopy; Raman spectroscopy and scattering
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Correspondence Address Kellerman, D.G.; Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya st., 91, Russian Federation
Publisher Elsevier Ltd
CODEN MCHPD
Language of Original Document English
Abbreviated Source Title Mater Chem Phys
Source Scopus